Fenton 原位化学氧化法修复有机污染土壤和地下水研究.pdfVIP

第 20 卷 第 78 期 化 　学 　进 　展 Vol. 20 No. 78 2008 年 8 月 PROGRESS IN CHEMISTRY 　Aug. , 2008 Fenton 原位化学氧化法修复有机污染土壤和 地下水研究 崔英杰 　杨世迎 　王 　萍 　贾永刚 ( 中国海洋大学环境科学与工程学院 海洋环境与生态教育部重点实验室 　青岛 266100) 摘 　要 　Fenton 高级氧化技术在废水处理领域已得到深入研究 。近年来 ,该技术在国外有机污染土壤 和地下水原位修复中受到越来越多的重视 ,而在国内相关领域则鲜有报道 。虽然国外已有工程试验 ,但 目前 对 Fenton 试剂降解土壤和地下水中有机污染物的研究尚处于基础阶段 。本文主要综述了Fenton 技术修复有 机污染土壤和地下水的发展过程和反应基本机理的研究进展 ,并针对修复中存在的问题进行了展望 。 关键词 　土壤地下水修复 　原位化学氧化 　Fenton 技术 　自由基机理 ( ) 中图分类号 : X1312 ; X1313 　文献标识码 : A 　文章编号 : 1005281X 2008 078119606 Organically Polluted Soil and Groundwater Remediation by in situ Fenton Oxidation Cui Yingjie 　Yang Shiying 　Wang Ping 　Jia Yonggang ( The Key Laboratory of Marine Ecological Environment , Ministry of Education , College of Environmental Science and Engineering , Ocean University of China , Qingdao 266100 , China) Abstract 　This paper provides an uptodate overview of the progress of in situ Fenton oxidation in remediation of soil and groundwater polluted by organic pollutants. As one of the advanced oxidation technologies , Fenton oxidation has been deeply researched in wastewater treatment. Recently , Fenton oxidation attracts more and more attentions in organically polluted soils and groundwater remediation. Fenton reagent has been constantly modified from traditional Fenton reagent in acid reaction to modified Fenton reagent in natural. The rate of degradation has being improved , and the technology is being applied in field scale. The mechanism for the Fentons degradation of the organic pollutan