毕业设计（论文）-Li-Ni-Mn-O体系正极材料的合成工艺与性能研究.docVIP

摘 要 由于市场化的锂电池正极材料容量低、成本高，难以满足电子产品和设备对高容量及低成本的要求，近年来容量高、价格低廉和循环稳定性好的富锂正极材料正引起广泛关注。 本文在综合评述锂离子电池及其正极材料研发现状的基础上，以提高锂离子电池性能、降低电池成本为目的。通过比较不同制备方法的优劣后我们采用了溶胶凝胶法制备层状结构Li1.13Ni0.3Mn0.57O2材料7.5:1:1.5制作的正极材料具有明显优势，这种比例的电池比容量高达280mAh/g而且比容量保持率也能达到83.6%。循环的稳定性和循环的效率方面这种比例电池也有很大的性能优势，在循环平稳的情况下效率平均能达到88%左右并且都高于其他比例的电池，所以我们认为这种比例的电池具有很好的电池性能。 关键词：锂离子电池；富锂正极材料；电化学；溶胶凝胶法  Abstract As the cathode material of lithium battery capacity market low, high cost, difficult to meet the requirement of high capacity and low cost requirements of electronic products and equipment, in recent years, high capacity, low price and good cycling stability of the rich lithium cathode material is causing widespread concern. On the base of reviewing the development of lithium ion batteries and cathode materials, in order to improve the performance of lithium ion battery, reduce the cost of the cell for the purpose of. Through the comparison of different preparation methods we adopted by layered Li1.13Ni0.3Mn0.57O2 lithium rich materials by sol-gel method. We studied the effects of different sintering temperature on the structure of the material, finally reached 900 ℃ sintering temperature material structure best. In battery testing process we try different proportion of active substances and acetylene black dosage and effect on electrochemical properties of cathode materials for lithium ion batteries under different current densities. In the specific capacity and capacity retention rate than, active substance, the proportion of PVDF and acetylene black as cathode material 7.5:1:1.5 production has obvious advantages, the proportion of the battery capacity of up to 280mAh/g and keep the rate can reach 83.6% capacity. Also have good performance in the cycle stability and cycle efficiency aspect of the proportion of cells in the cyclostationary case, average efficiency can reach about 88% and higher than other proportion of the battery, so we think that the proportion of the battery has high research value. K