冷冻干燥微波消解icpms法测定牦牛乳中的微量元素.pdfVIP

356 2009, Vol. 30, No. 18 食品科学 ※分析检测 1 2, 1 3 张玉玉 ，唐善虎 * ，徐进勇 ，马 莺 (1.成都理工大学材料与化学工程学院，四川 成都 610059 ；2.西南民族大学生命科学与技术学院，四川 成都 610041 ；3.哈尔滨工业大学食品科学与工程学院，黑龙江哈尔滨 150001 ) 采用真空冷冻干燥技术、微波消解方法处理牦牛乳样品后，直接用电感耦合等离子质谱仪(ICP-MS)测定 了牦牛乳中的14 种微量元素。外标法绘制标准曲线，相对标准偏差1.80%～4.50% ，加标回收率95.61%～102.90%。 分析结果表明牦牛乳中含有人体中存在的多种微量元素，其干物质中的微量元素含量平均值分别为Cu 0.340 μg/g ， Zn 50.65 μg/g，Fe 16.12 μg/g，Mn 0.843 μg/g，Mo 0.170 μg/g，Co 0.023 μg/g，Ni 0.522 μg/g， Ti 0.001 μg/g，V 0.105 μg/g，Li 0.056 μg/g， Be 0.003 μg/g，Bi 0.029 μg/g ，Pb 0.305 μg/g， Cd 0.014 μg/g 。 牦牛乳；微波消解；I C P - M S ；冷冻干燥；微量元素 Freeze-drying and Microwave Digestion Followed by ICP-MS for the Determination of Trace Elements of Yak Milk 1 2, 1 3 ZHANG Yu-yu ，TANG Shan-hu *，XU Jin-yong ，MA Ying (1. College of Materials and Chemical Engineering , Chengdu University of Technology, Chengdu 610059, China； 2. College of Life Science and Technology, Southwest University for Nationalities, Chengdu 610041, China； 3. College of Food Science and Engineering, Harbin Institute of Technology, Harbin 150001, China) Abstract：Yak milk samples were freeze dried in a vacuum chamber and digested using microwave, and the digestion solution was directly injected into inductively coupled plasma-mass spectrometry (ICP-MS) for quantitative determination of trace elements by external standard method. The relative standard deviations of precision of this method were between 1.80% and 4.50%, and the spiked recoveries ranged from 95.61% to 102.90%. Yak milk contained a variety of trace eleme