一种新型固体缓蚀剂的合成及性能尹成先.pdfVIP

239 精 细 化 工 V o .l 23, N o. 9 2 0 0 6 9 FINE CHEM ICALS Sep t. 2 0 0 6 * 1, 2 2 1 2 尹成先 , 冯耀荣 , 兰新哲, 白真权 ( 1. , 7 10055; 2. , 7 10065 ) : , , , : n ( ) Bn () = 1B211; 315 h, 3 h, , 80% ; Q - ( C l ) = 157 305 m g LCO 2 31 5 M P a 120 e 20 M Pa, N80 85% , : ; ; : TQ 223. 2 : A : 1003- 5214 ( 2006) 09- 0930 - 0 3 Synthesis and Properties of New Solid Inhibitors 1, 2 2 1 2 Y IN Cheng-x ian , FENG Y ao-rong , LAN X in- zhe , BA I Zhen-quan ( 1. The P rec ious M ental E ng ineer ing Inst itute, X ican Un iv er sity of A rch itecture Tech nology, X ican 710055, Shaanx i, Ch ina 2. The K ey L aboratory f or M echan ical and E nv ironm ental B ehav ior of T ubu lar, CNP C, X ican 7 10065, Shaanx i, Ch ina ) Abstract: U sing d mi eric dibasic ac id, diethylenetriam ine and ch loroace tic acid as raw m ateria ls, a new type quaternary amm on ium sa lt of doub le-a lky l and doub le-annular mi idazo line so lid inh ib itor w as synthesized through am idation, cyc lizat ion and quarternarizat ion reactions. By orthogonal expermi ent, the best mo l proportion o f dmi eric d ibasic ac id and diethy lenetriam ine is 1B211, the tmi e of am idation reaction is 315 h, and that o f quarternariza tion react ion is 3 h. Infrared spectroscopy proved the product to be mi idazo line quat