形状记忆高分子材料性能评价的分子模拟研究.pdfVIP

! 116 ! 材料导报:综述篇 2010 年9 月( 上) 第24 卷第9 期 张慧军, 岳 红, 刘 倩, 陈 冲 (, 710129) 分子模拟在新材料研究领域中有着广泛的应用介绍 形状记忆高分子材料的分类, 阐述 用分子模 拟形状记忆材料性能的理论,分析 统计弹性力学原理, 提出 构建模型和模拟的方法,概述 近年来分子模拟的研 究现状及存在的问题, 并展望 形状记忆高分子材料的发展 :T B34 : A Performance Evaluation of Shape Memory Polymer by Molecular Simulation ZHANG Huijun, YUE Hong, LIU Qian, HEN hong ( Department of Applied hemistry, Northw estern Polytechnical University, Xi an 710129) Abstract Molecular simulation is widely used in the study field of new materials. T he categories of shape memory polymer are introduced. Based on rubber elasticity theory, the construction and simulation methods are also elaborated. The current status in molecular simulation is also presented and problems of shape memory polymer are proposed. It makes prospects for the development of shape memory polymer materials. Key words shape memory polymer, performance, evaluation, molecular simulation [ 10] , 0 ( P G) , , ,, P G , ( 4) [ 11- 14] , [1- 6] pH ,; , , [ 7] 1 ( SMP) , , , , 1981 ,, E= 3Vk 2g T : T ( Tm ) ;g ; k , ; = / ,4 : ( 1) ; V ; V= N /[M ( 1- 2M / M )] (