碳纳米管阵列超双疏性质的发现_翟锦.pdfVIP

* ­ 翟 锦 李欢军 李英顺 李书宏 江 雷 ( 100080) , . , , , , 15815 ? 11 5b, 0 ? 110b. , , 171? 015b16 1? 110b. , , , 166b, 8b. . P . , , DISCOVERY OF SUPER- AMPHIPHOBICPROPERTIES OF ALIGNED CARBON NANOTUBE FILMS ­ ZHA I Jin LI Huan-Jun LI Y ing- Shun LI Shu-Hong JIANG Lei ( Institute of Chemistry , Chinese A cademy of Sciences , Beij ing 100080, China) Abstract Severa kinds of a igned carbon nanotube( ACNT ) fi ms w ith different morpho ogies w ere prepared by pyro ysis of meta phtha ocyanines. Super-hydrophobic and super-amphiphobic properties were studied in detai . The ACNT fi ms with fair y uniform ength and externa diameter show ed super-hydrophobic and super-oi eophi ic proper- ties, with contact ang es( CAs) of 15815 ? 115b and 0 ? 110b for water and rapeseed oi respective y. After f uorina- tion treatment, these ang es became 17 1 ? 015b and 161 ? 110b, respective y , showing both super- hydrophobic and super-oi eophobic properties, typica of a super- amphiphobic surface. For ACNT fi ms w ith otus- ike structures, not on y w as the morpho ogy c ose to that of otus eaves, but their super- hydrophobic properties w ere a most the same a- so . The CA and s iding ang e for water of this kind of fi ms were 166b and 8b, respective y. These super- hydrophobic and super-amphiphobic properties are caused by the nanostructures and the combinat ion of nanostructures and micro- structures on the surface. This discovery may provide a new method to study super- hydrophobic surfacePinterface ma- teria s w ithout f uorine.