硅灰石的X射线荧光光谱分析_罗明荣.pdfVIP

26 3 V o l. 26, N o. 3 2007 6 RO CK AND M INERAL ANALY SIS June, 2007 : 0254 - 5357 ( 2007 03- 0245- 03 硅灰石的X射线荧光光谱分析 罗明荣 (, 643010 : 将 X 射线荧光光谱法应用于硅灰石中 SiO CaOA l O F e O P O M gOK OT iO M nO 的同时快速 2 2 3 2 3 2 5 2 2 测定试样和混合熔剂的 量比为 1 B 10, 在此稀释比时试样在熔剂中的分散度 ( 浓度 适当, 可适应各 个组分的 测定熔融法分解试样有效地消除了试样的粒度效应和矿物效应采用理论A系数校正法克服了基体吸收及增 强效应用国家标准物 和样品验证了方法的精密度和准确度, 其结果与化学分析值相符 : X 射线荧光光谱法; 硅灰石; 混合熔剂; 快速测定 : O 657. 34; P578. 94 : B X-ray F luorescence Spectrom etric Analysis ofW ollastonite LUO M ing-rong ( Inspec tion Department o f A tlantic C hina W e dl ing Consumab el s, Inc., Z gi ong 643010, C hina) Abstract: A m ethod fo r the determ ination of S iO , CaO, A l O , Fe O , P O , M gO, K O, T iO , M nO in w o llastonite samp les by 2 2 3 2 3 2 5 2 2 X- ray fluorescence spectrom etry w ith fu sion sam ple preparation w as repo rted in th is paper. A m ix ture o f lithium tetrabora te( L i B O 2 4 7 and lith ium m etaborate( L iBO2 in a ratio o f 2 B 3 and m ass ratio o f sam ple to flux o f 1 B 10 w ere used w ith sample fu sion condition of 1200e and 15 m in. Fu sion sample preparation me thod effectively elmi inated the g ranular ity effect andm ineral effect. A nd the effects o fm atrix absorption and enhancem ent w ere elmi inated by the theoretica l A-coeffic ient correction me thod.