厦门大学有机化学课程试卷.pdfVIP

厦门大学《有机化学》课程试卷 化学化工学院化学系2002 级各专业 主考教师：陈毅辉 试卷类型：（A卷） 1. Answer the following questions (30 pts.) (1) The IUPAC rules permit the use of common names for a number of familiar phenols and aryl ethers. These common names are listed here along with their systemaic names. Write the structure of each compound. (a) Vanillin (4-hydroxy-3-methoxybenzaldehyde): a component of vanilla bean oil, which contributes to its characteristic flavor (b)Thymol (5-isopropyl-2-methylphenol) : obtained from oil of thyme (c) Gallic acid (3,4,5-trihydroxybenzoic acid): prepared by hydrolysis of tannins derived from plants (2) Which one of the C H isomers shown has its λ at the longest wavelengh in the UV 5 8 max spectrum ? (a) (b) (c) (3) P henylbutazone is a frequently prescribed antiinflammatory drug. It is prepared by the reaction shown. CH (CH ) CH(CO Et) + C H NHNHC H C H N O 3 2 3 2 2 6 5 6 5 19 20 2 2 Diethyl butylmalonate Phenylb utazone What is the structure of phenylbutazone ? (4) The compound triptyene may be prepared as shown. What is compound A ? F + Compound A Mg, THF Br (C 14H10) heat triptyene (5) A synthesis of the analgesic substance phenacetin is outlined in the following equation. What is the structure of phenactin ? (1) CH CH Br, NaOH