徐利军U200811155不同化学合成法对BNT陶瓷结构及性能的影响.docVIP

不同化学合成法对BNT陶瓷组织结构及性能的影响 摘要 钛酸铋钠Na0.5Bi0.5TiO3 () 具有铁电性强压电常数大、介电常数小机械、电子、精密控制等领域。Na0.5Bi0.5TiO3钙钛矿相形成的主要因素。当NaOH浓度提高到8mol/L时，才可形成单一钙钛矿相Na0.5Bi0.5TiO3，而且随着NaOH浓度的提高，Na0.5Bi0.5TiO3结晶性得到提高。Bi/Ti摩尔比对产物的成分和形貌有较大影响，当Bi/Ti为1:1.6和1:时生成。在反应温度、保温时间和碱浓度保持不变的情况下，Bi/Ti比产物Bi/Ti摩尔比，CO(NH2)2/Bi摩尔比对Na0.5Bi0.5TiO3有较大的影响。CO(NH2)2/Bi摩尔比，Na0.5Bi0.5TiO3，约为1 μm的球状颗粒分散20℃。这可能是由于水热法合成的陶瓷粉末颗粒比较细小，表面活性较好，表面能和晶粒界面能高。 水热陶瓷样品在升温过程中出现两个介电峰，并且介电反常峰出现弥散相变的现象，表现出典型弛豫型铁电体的特性。介电常数在整个温度范围都有不同程度的频率依赖。这主要由于成分起伏而导致产生慢响应空间电荷极化。 关键词：钛酸铋钠水热法Abstract Sodium bismuth titanate, Na0.5Bi0.5TiO3 (BNT),?has strong ferroelectrics, high piezoelectric coefficient and low dielectric constant. It can be widely used in machinery electronics, precision?control and other areas. However, solid state reaction is widely used in synthesising ceramic, this method will easily bring in impurity, and it can cause nonuniform composition, what’s worse, synthesizing time is too long, and temperature is too high. Synthesizing methods at lower temperature have the advantages that powder is uniformity, equal size and active fine. There’s no reports about the aspects. The BNT ceramic was synthesized in two different ways: solution combustion method and hydrothermal method. Then, we can study the effects between synthesis methods, preparation technology, composition and structure make to piezoelectric properties of the BNT ceramic. The concentration of NaOH is the main fact to influence the synthesis of perovskite phase with hydrothermal method. Only when concentration of NaOH is 8 mol/L can it form a single perovskite phase, with the rise of concentration of NaOH, crystallization behavior of Na0.5Bi0.5TiO3 improved. The mole ratio of Bi to Ti make a great influence to morphology and composition. When the mole ratio of Bi to Ti is 1:1.6 and 1:1.8, nano-fiber can be shown to us. With mole ratio decrease, more nano-fiber was got. Urea bismuth nitrate pentahydrate mole ratio has very big effect on synthesizing perovskite phase sodium bismuth