3,5-二甲基盐酸美金刚胺的IRMS谱图研究.pdfVIP

IR/MS study on 3,5-dimethyladamantanamine hydrochloride salt 1 2 3 3 3 Ren Huixue , Lin Jimao , Qi Yinshan , Zhang Yeqing , Zhang Qinghe 1.School of Envirormental Engneering.Shangdong Jianzhu University, Jinan, Shandong (250010) 2.School of Chemistry and Chemical Engineering Shandong University Jinan, Shandong (250001) 3.ZiBo HuaLian Mining Industry CO.,LTD Zibo, Shandong (256100) E-mail ：huixuemail@ Abstract Infrared spectra shows that the characteristic absorptions of 3,5-Dimethyladamantanamine hydrochloride are the overtones of NH3+ deformation vibrations at frequencies of 3171.9 cm-1, 2993.8 -1 + -1 cm , and the overtones involving NH3 deformation vibration in 2600-2000 cm region. The + -1 NH3 asymmetry and symmetry deformation vibrations were found at 1596.2 and 1503.5 cm with a medium intense. The 1311.6 cm-1 and 1192.2 cm-1 are attributed to rocking vibration and C-N bond stretching vibration respectively. The absorption in 2850-2950 cm-1 indicate the presence of CH , CH 3 2 and CH groups. The ESI mass spectrum only gives three peaks but shows essential information of molecular structure. The ]M+H] ion undergoes elimination of NH3, forming m/e 163. The m/e 107 peak is pro