AMV及其醇解_胺解型柴油降凝剂的合成与性能研究.pdfVIP

27 10 精 细 化 工 Vo.l 2 7, No. 10 2 0 1 0 1 0 FINE CHEM ICALS O ct. 2 0 1 0 AMV 李 娜, 李光进, 韩 帅, 严世强* ( , 730000) : ( AMV) , n ( -) n ( ) n ( ) = 41 2, 85 , 5 h, 12% ( , ) , AMV 01% (, ) , 3 10149 , 132 ; , 01% , 3 101611 , 253 : AMV ; ; ; ; ; ; : TE62481 : A : 1003- 52 14( 20 10) 10- 1031- 04 Study on the Synthesis, A lcoholysis and Am inolysis of D iesel Flow Impro er AMV * LI Na, L I Guang-jin, HAN Shuai, YAN Sh-i q iang (C olleg e of Chem is try and Chem ical E ng ineering, L anzhou Un iversity, L anzhou 730000, Gansu, Ch ina) Abstract: The synthesis, alcoholysis and am inolysis of -m ethy l m ethacry late ester-m ale ic anhydrid- v iny l acetate(AMV ) w as described and characteri ed in th isw ork. The solidifying po int( SP) and cold filter plugg ing point ( CFPP ) depression effects of the AMV terpolym er and its alcoholysis and am inolysis products w ere determ ined. The terpolym er w ere characteri ed by IR. The AMV terpolym er was synthesi ed at the m olar ratio ( 412 ) of -m ethyl m ethacrylate ester, m ale ic anhydride, v iny l acetate w ith 12% in itiator at 85 for 5 h. W ith 01% add itive dosage, the AMV terpolym er can reduce the SP and CFPP of three kinds of diesel o ils( obtained from Petro Ch ina Lan hou Petrochem ical Com pany) by 10, 14, 9 and 1, 3, 2 , respectively. The alcoholysis and am inolysis of the AMV polym er were also carried out. W ith 01% additive dosage, the am inolysis products through octadecylam ine cou ld