Preparation of Nitrogen-doped TiO2 Nanoparticle Catalyst and Its Catalytic Activity under Visible Light.pdfVIP
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Preparation of Nitrogen-doped TiO2 Nanoparticle Catalyst and Its Catalytic Activity under Visible Light.pdf
维普资讯
Chin.J.Chem.Eng.,15(6)802—807(2007)
Preparation ofNitrogen-doped TiO2NanoparticleCatalystand Its
CatalyticActivityunderVisibleLight
BYuHu鼍ng(於煌),ZHENGXuxu!~ ),YINZhongyi(殷钟意),TAoFeng(~丰),FANG
eibei(房蓓蓓)andHOUKeshan(侯可 山)
CollegeofEnvironmentandBiOengineering,ChongqingTechnologyandBusinessUniversity,Chongqing400067,
China
Abstract N—dopedTiO,nna oparticlephOtOcata1ystswerepreparedthroughasol—ge1procedureusingNH4C1as
thenitrogensourcena dfollowedbycalcinationatcertaintemperature.Systematicstudiesfortheprepraationpa—
rametersnadtheirimpactonthestructurenadphotocata1yticactivityunderulrtaviolet(UV)nadvisible1ightirra—
diationwerecarriedout.Multipletechniques(XRD,TEM ,DRIF,DSC,na dXPS)werecommandedtochraacterize
thecrystalstructuresandchemicalbindingofN—dopedTiO,.Itsphotocatalyticactivitywasexaminedbythedeg—
radationoforgna iccompounds.ThecatalyticactivityoftheprepraedN—dopedTiO,nanoparticlesundervisible
1ight(2400nm)irradiationisevidencedbythedecompositionof4一chloropheno1.showingthatnirtogenatomsin
theN—dopedTi0,nnaoparticlecatalystraeresponsibleofrthevisiblelightcatalyticactivity.TheN—dopedTiO,
nna oparticlecatalystprepraedwiththismodifiedrouteexhibitshighercatalyticactivityunderUV irradiation in
conrtasttoTiO,wihtoutN—doping.Itissuggestedthatthedopednitrogenhereis1ocatedattheinterstitialsiteof
TiP2lattice.
Keywords photocatalysis,Ti02,visiblelight,nirtogen—doping,prepraation
1 INTRoDUCTIoN N—doped Ti0, and a relatively environmentally
Sincethereportofphotoelectrochemicaldecom— friendlyNH4Clasnitrogensource.Mulfipleanalytic
position of wateron titanium dioxide electrode in
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