Reactions Between Humic Acid Solutions and Excessive ClO2 or Cl2.pdfVIP

维普资讯 JournalofDonghuaUniversity (Eng．Ed．)Vo1．24．No．5(2007) ReactionsBetweenHumicAcidSolutionsandExcessiveCIO2orC12 GEYuan．xin(葛元新) ，ZHUZhi．1iang(朱志良)，V／IAHong．mei(-~ 梅)，ZHAOJian-fu(赵建夫) j “teKYLaborator5rofPollutionControlandl~esourceReuse．S(hoolofEnviromnentalScienceandEngineering，Ton14jiUniversity Shangkai200092，China 2 No．1EnuirotHnnta{ i0，dtoringStationofMinhangDistrict，Sbanghai201i00，Ckina Abstract：Reactions Ix：tween humic acid solutions and Agency)，ithasbeen proved thattheuse ofchlorine in excessiveC102orCI2havebeeninvestigated．Undervarious waterdisinfection may lead to the formation ofharmful disinfection by—products (DBPs)ll-3j experimentalconditions．theremovalefficiency ofTOC， ． These DBPs， Uv254and l0from humicacidsolutionswereexamined- includingthewell—knownTHM s，haloaceticacids(HAAs) Therelationship between the removalefficiency and the andothers．are prod uced by chemicalreactionsbetween consumptionofC102orCI2wasdiscussed．Theresults theapplied chlorineand awidevariety oforganics．In showedthatthemaximumdemandofC102was2．19mg／mg recent years， the widespread contamination of water ToC for the hmu ic acid solution under the experimental resourcesby human activity has resulted in the overuse of conditions，andthatofCI2was1．88 rag／ragTOC．The chlorinesjnwatertreatment，which leadsto theincrea,~ of variationtendencyofC102consmu ptionwassmi ilartothat formation ofDBPs． These DBPshave been identifide as 0fCl，．TOC ofhmu icacid solutionsdecreased15．2％ and cancer—causing reagents in the last three decadesL ． Since 15．6％ afterthereactionwithC102orCl2respectively． then。attempts havebeenmadet0sw