新型非离子型反应性乳化剂的合成及其应用.pdfVIP

31 3 ( ) ol.31 No. 3 2010 6 Journal of Qingdao University of Science and Technology(Natural Science Edition) Jun.2010 :2010) , , * ( , 266042) : 马来酸酐与饱和脂肪醇酯化反应得到马来酸酐单酯羧酸;聚乙二醇和丙烯酸反 应得到聚乙二醇丙烯酸单酯; 二者在催化剂的作用下反应, 得到马来酸酐丙烯酸 的非 离子 反应性乳化剂进行提纯后, 经红外鉴定目标产物, 结构正确将合成的反应性乳 化剂用于 St/ MMA/ BA 的乳液聚合中, 得到的苯丙乳液单体转化率为958 %, 凝胶率 009 % , 固含量425 %,粒径为80~ 100 nm作为对比, 将传统乳化剂十二烷基硫酸钠 (SDS) 应用到该聚合中, 结果发现, 由反应性乳化剂制的苯丙乳液的耐电解质稳定性和储 存稳定性等得到较大提高 : 反应性乳化剂;马来酸酐;丙烯酸;乳液聚合 : T Q 423 : A Synthesis and Application of the New Nonionic Reactive Surfactant CAI Jian, CHENXuegang, U Shanpu ( Key Laboratory of Rubberplastics, Ministry of Education, Qingdao U niversity of Science and T echnology, Qingdao 266042, China) Abstract: The nonionic reactive surfactant was prepared with monododecy l male at e and monopolyglycol acrylate. M onododecy l maleate was synthesized by using maleic an hydride and fatty alcohol, while monopolyglycol acrylate was produced using poly(eth ylene oxide) and crylic acid. The structure of reactive surfactant was confirmed by IR after purification. T he surfactant was then applied in the semicontinuous polymerization of St/ MMA/ BA. The conversion of monomers was 958 %, the gel fraction was 009 %, the mass fraction of solid content of emulision was 425 % , and the particle size of latex was about 100 nm. A nonreactive surfactant sodium dodecyl sulfate ( SDS) was also used for the polymerization. It was found that the latexes produce by using the reactive surfactant have a better dispersion stability at high electrolyte concentration. Key words: reactive surfactant; maleic anhydride; crylic acid; emulsion polymerization