La0.875Sr0.125MnO3粉体及块体的制备和性能研究.pdfVIP

R37 La Sr MnO 粉体及块体的制备与性能研究 0.875 0.125 3 陈树涛 周洋 颜世韬 赵鸿滨 李世波 翟洪祥 （北京交通大学机械与电子控制工程学院，北京 100044 ） 摘要：锰酸锶镧陶瓷具有室温附近的金属体-绝缘体相变效应，导致其红外发射特性发生明显变化，是一种极具 应用潜力的航天器智能热控材料。本文采用固相反应法合成 La0.875Sr0.125MnO3 粉体，并采用冷压成型-常压烧结 工艺制备 La0.875Sr0.125MnO3 块体材料。研究了合成与制备工艺对 La0.875Sr0.125MnO3 材料的纯度、成型质量以及烧 结体性能的影响。结果表明，La0.875Sr0.125MnO3 粉体具有较宽的合成温度范围；块体材料的制备宜采用两步法， 烧结温度不应低于 1300°C ；采用较低的成型压力、适当添加粘结剂以及采用冷等静压成型都有利于提高块体材 料的烧结质量。 关键词：锰酸锶镧；固相反应；制备工艺；可变发射率 Preparation and Properties of La Sr MnO Powder and 0.875 0.125 3 Block materials CHEN Shutao, ZHOU Yang, YAN Shitao, ZHAO Hongbin, LI Shibo, ZHAI Hongxiang (School of Mechanical Electronic Control Engineering, Beijing Jiaotong University, Beijing 100044, P. R. China) Abstract: (La,Sr)MnO3 ceramics shows a metal–insulator transition near room temperature, and its infrared emittance property significantly changes at the transition temperature. Therefore, (La,Sr)MnO3 can be used to automatically control the emissive heat transfer from a spacecraft. In this paper, La Sr MnO powder was synthesized 0.875 0.125 3 by solid phase reaction, and the La Sr MnO block material were prepared by cold 0.875 0.125 3 compression molding combining with normal pressure sintering. The effect of preparation technologies on purity, molding quality and properties of La0.875Sr0.125MnO3 wer