高性能轮胎-冬季轮胎.pptVIP

Principle of the study Raw compound properties Raw compound properties Mechanical properties Mechanical properties Mechanical properties Mechanical properties Dynamic properties Correlations ... Viscoelastic properties Viscoelastic properties Viscoelastic properties Viscoelastic properties Conclusions * Shaping your future February 2002 High performances precipitated silicas for winter tire tread Silica Systems Tire Technology Expo , Hamburg, February 20-22, 2002 High performances precipitated silicas for winter tire tread 0 50 100 150 200 250 300 94 95 96 97 98 99 00 01 02 03 04 05 10 VZ H ST Winter Replacement market in 2000 : 130 M units ? Forecast for 2005 : 145 M units Market growth : circa 2% per year. The high speed rated tires are replacing the low rated ones. Snow tire segment is definitively taking a significant market share European passenger tire market 0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100% 94 95 96 97 98 99 00 01 02 03 04 05 VZ H ST Winter M. Tires A basic recipe was studied in order to compare CB to precipitated silicas, as well as the best polymers system. 5 polymer systems were used : 2 emulsion polymers and 3 with solution SBR. In each case a 40 phr cis BR was used. 3 different fillers : 1 CB (N234) and 2 precipitated SiO2 (Z1115 MP Z1165 MP). The oil content was adapted in order to get the same oil quantity in each recipe. TESPT is a function of the silica total surface. N330 was added to compensate the variable amounts added with the silane. Recipes of the study Polymers and fillers characteristics Polymers characterizations Highly dispersible precipitated silicas characterizations Recipes used for the study * TESPT supported on N330 : 50/50 ** sSBR 40% is already containing oil NR 60 N 234 55 0 5.2 60.2 27.5 27.5 Z1165 55 10.4 0 60.2 BR cis 1-4 40 Z1115 63 9.4 0.5 67.7 eSBR 1502 60 N 234 60 0 5.2 65.2 27.5 27.5 Z1165 60 10.4 0 65.2 BR cis 1-4 40 Z1115 68