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摘　要：　研究了轻烃芳构化ZnNi/HZSM-5催化剂的失活类型，认为积炭失活是改性ZSM-5催化剂的最主要失活方式，经烧焦可恢复其催化活性。通过马弗炉静态烧焦和反应管动态烧焦，考察了再生温度对烧焦过程的影响，推测出再生模式。在小型连续式100 mL固定床装置上在宏观热效应方面模拟了工业烧焦再生过程，认为烧焦是一个从外向内逐步扩散的过程，在催化剂上会形成热点，在烧焦再生的影响因素（再生气的氧含量、空速，再生最高温度和时间等）中，再生最高温度的影响是最显著的，只有达到575才能恢复催化剂活性；而再生气空速和氧含量决定了再生时间。在所考察的3种再生方案中，确定了最佳的再生方案（低起燃温度，一次烧焦）。该方案不仅比以往方案省时50％，而且再生后ZnNi/HZSM-5催化性能恢复好，稳定性不变。　　关键词：　ZnNi/HZSM-5；　再生；　芳构化；　轻烃　　中图分类号：O643.32　　　　文献标识码：A Systematic Studies on the Aromatization of Light Hydrocarbon()——Investigation on Reactivation Methodology for ZnNi/HZSM-5 Catalyst Li Hongyang，Cheng Zhilin，Gui Jianzhou，Liu Ningning，Wei Li，Zhang Xiaotong,Ding Hongsheng，Qi Kexin，Ma Zhongge，Song Lijuan，Sun Zhaolin*(Department of Applied Chemistry, Fushun Petroleum Institute, Liaoning Fushun 113001， China) Abstract：After studying the deactivation type of ZnNi/HZSM-5 catalyst of aromatization of light hydrocarbon, the conclusion was drawn that carbon deposition was the main one of modified ZSM-5 and the catalytic activity could be recovered by charking. The reactivation mode was presumed on the basis of the investigation of the influence of temperature on reactivation process by static charking in muffle furnace and dynamic charking in reactor. Reactivation process simulating industrial charking process at macroscopic calorific effect was studied in 100 mL miniature continuous fixed-bed reactor. The result shows that charking was a diffusion process forming hot spot in catalyst from outer to inner and maximum reactivation temperature was the most important factor among the influential ones including oxygen content, space velocity, time and maximum temperature. Catalytic activity could be recovered only when temperature was higher than 575℃. Meanwhile, reactivation time was determined by space velocity and oxygen content. The best scheme (low initial burning temperature and single charking) was confirmed from the comparison of the three reactivation ones. According to the third scheme, reactivation time was cut down b