稀土硝酸盐促进的铝合金锌系磷化成膜过程修改.doc

(稀土硝酸盐促进的铝合金锌系磷化成膜过程 张圣麟1. * 张小麟2 1 河南师范大学 化学与环境科学学院 河南省 新乡市 453007 2 河南工业大学 化学化工学院 河南省 郑州市 450052 [摘要] 采用扫描电镜(SEM)、X射线衍射(XRD)及能谱(EDX)和电化学测试的方法，研究了稀土硝酸盐（REN）对6061铝合金锌系磷化成膜过程的影响，结果表明，少量的稀土硝酸盐添加到磷化液中可以提高磷化成膜速度和细化晶粒，改变磷化膜的组成成份，但稀土硝酸盐（REN）本身并不构成磷化膜的组成成份，它实质上是具有良好载氧能力的促进剂，具有良好的成核促进作用和阴极去极化作用，与在不含稀土硝酸盐（REN）的磷化液中所形成的磷化膜相比，铝合金在含有稀土硝酸盐（REN）磷化液中所形成的磷化膜具有较低的化学活性，其耐蚀性得到提高，在所研究的工艺条件下，最佳硝酸盐含量为20～40mg/L。 [关键词] 稀土硝酸盐（REN）；磷化； 铝合金； 促进剂； [中图分类号] TG178 [文献标识码] A Zinc Phosphating Accelerated by Rare Earth Nitrate on Aluminum Alloy Zhang Sheng-lin 1. * Zhang Xiao-lin 2 1. Chemistry Environmental Science College, Henan Normal University Henan Xinxiang P.R. China 453007 2. School of Chemistry and Chemical Engineering, Henan University of Technology Henan Zhengzhou, 450052, P.R. China [Abstract] Zinc phosphate coatings formed on 6061-aluminum alloy, after dipping in zinc phosphating solutions containing different concentrations of rare earth nitrate (REN), were studied by scanning electron microscopy (SEM), X-ray diffraction (XRD), energy-dispersive X-ray (EDX) and electrochemical measurements. The overall objective was to learn more about the influence of REN on the zinc phosphate coatings of aluminum alloy. This study reports that REN possesses virtually good capacity to transport oxygen and debase polarization of cathode, it can not only markedly accelerate phosphate deposition but also consumedly decrease zinc phosphate crystal size. The chemical composition of zinc phosphate coatings varies as the REN concentrations of the phosphating solutions change, but REN is not incorporated into zinc phosphate coatings. REN acts as accelerator and has the function of activating the aluminum alloy surface. The phosphate coatings formed in phosphating solutions containing REN have lower chemical reactivity, comparing with phosphating coatings formed in phosphating solutions containing free-REN, and its corrosive resistance has been improved. [Keywords] rare