粘结剂含量对铝电解槽阴极捣固糊质量的影响的研究.pdfVIP

2ndintemationalca灿nconf．erenceinChina 第二届国际铝用炭素技术会议 粘结剂含量对铝电解槽阴极捣固糊质量的影响研究 周国斌 (中国铝业贵州分公司，贵州贵阳550014) 摘要：随着大型铝电解槽的发展，对阴极捣固糊性能、品质提出了更高的要求。在实验室条件下，利用RD公司小型试验 设备，改变贵州分公司阴极捣固糊现有生产配方的粘结剂量，研究粘结剂量对捣固糊性能的影响。对捣固糊焙烧前后常规理 化指标进行了分析检测，还对导电率、导热率、收缩／膨胀率和抗钠侵蚀性等特殊指标进行了深入和细致的研究。指出了贵州 分公司阴极捣固糊在收缩率及抗钠侵蚀性与国外捣固糊存在的差距，认为利用分公司现有的粘结剂，改变粘结剂量对提高阴 极捣固糊质量作用不大，只有从配方着手，寻找合适的原料、添加剂及粘结剂，降低阴极捣固糊在电解槽焙烧启动时的收缩 率，提高抗钠侵蚀性，才是提高阴极捣固糊质量的根本。 关键词：电解槽；阴极捣固糊；粘结剂；收缩率；抗钠侵蚀性 EffectofBinderContentonCathode Paste RammingQuality ZHOuGuo．bin Branch (GuizhouofCHALCO，Guiyang，Guizhou550014) the of aluminumreductioncellsthe andbetter of Abstract：Withdevelopmentlarge··scale higherquality property cathode are effectofbindercontentonthe of wasstudied rammingpasterequired．The propertyrammingpaste by useofbenchscaleunitsmadeRDCarbonLtd．to thebindercontentinthecurrent of by change productionrecipe of Branch cathode Guizhou undertheLabconditions．Theroutine of before rammingpaste propertiesrammingpaste andafter were and wasalsocarriedoutonelectrical bakinganalyzeddetermined．Thoroughstudy conductivity， ratioandresistancetosodiumcorrosion．Itisfoundoutthatthereexist thermoconductivity，shrinkage／expansion and cath— somedifferencesof ratioandresistancetosodiumcorrosionbetweenGuizhouBranchoverseas7 shrinkage ode is tomakea ofthe to thebinderthatisused rammingpaste．Itimpossible bigqualityimprovementpastechange inGuizhouBranch