稳定性二氧化氯溶液中二氧化氯存在形态的研究.pdfVIP

2001 年4 月 Apr. , 2001 第21 卷第4 期 Industrial Water Treatment Vol. 21 No. 4 贺启环, 谢慧芳 ( 南京理工大学环境科学与工程系, 江苏 南京 210094) [ ] , ( ClO ) ( ) 2 , , ClO ( ClO - ) , NaHCO - Na CO 2 2 3 2 3 ; , ClO , 2 H BO - Na B O 3 3 2 4 7 [ ] ; ; + [ ] T Q124.4 3 [ ] A [ ] 1005- 829X( 2001) 04- 0008- 03 Study of chlorine dioxide existence form in stabilized chlorine dioxide solution HE Qi uan, XIE Huifang (Dep t. of Environmental Science and Engineering, Nanj ing University of Science and Technology, N anj ing 210094, China) Abstract: Firstly depending on t eoretical analysis, t is paper suggests t at c lorine dioxide( ClO ) in stabilized 2 c lorine dioxide aqueous solution( stabilized solution) as a different existence form because of t e different stabi lizer used. On t e basis of t e analytical results of infrared spectrometry, paper c romatograp y , tyrosine color development reaction and t e assay of antiacid buffer capability, w e confirm t at c lorine dioxide in stabilized solution w it sodium percarbonate as stabilizer exists in t e form of c lorition ( ClO - ) and exists in NaHCO - 2 3 Na CO buffer system. W en t e stabilizer is sodium perborate, c lorine dioxide may be retained in t e solution 2 3 comprised of H BO - Na B O as a labile complex. T e results related above w ill ave important guide effect on