碳微线圈的气-液-固-固生长机理.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) 768 Acta Phys. Chim. Sin., 2006, 22(6) ：768 770 June [Note] 碳微线圈的气液 固固生长机理 文军 徐海涛 郭燕川 陈丽娟* (中国科学院理化技术研究所, 北京 100101) 摘要 碳微线圈具有类似DNA 的双螺旋结构, 通常以镍为催化剂, 噻吩为助剂采用CVD 法制备, 但是对于它 的生长机理人们仍不十分清楚. 本文发现构成碳微线圈的碳纤维由三条亚纤维组成, 提出了碳微线圈的气鄄液鄄 固鄄固生长机理, 并以此对实验事实做出合理解释. 关键词： 碳微线圈, 螺旋, 生长机理, 碳纤维 中图分类号： O649 Vapor Liquid Solid Solid Growth Mechanism of Carbon Micro coils LI, Wen鄄Jun XU, Hai鄄Tao GUO, Yan鄄Chuan CHEN, Li鄄Juan* (Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beiji ng 100101, P. R. China) Abstract Carbon micro鄄coils, which have double helix structure, are generally prepared by catalytic chemical vapor deposition of acetylene, using Ni as the catalyst. It is well known that the coils are formed because of the catalytic anisotropy, however the growth process of carbon micro鄄coils is still unclear. In this paper, it is reported that the fiber constructing the carbon micro鄄coil is composed of three sub鄄fibers. Referring to this experimental finding and known facts from the phase diagrams, a vapor鄄liquid鄄solid鄄solid growth mechanism of carbon micro鄄coils is proposed. In this mechanism every catalyst particle can be divided into two parts, one is liquid while the other is solid. The schematic growth process of the carbon micro鄄coil is shown. Carbon atoms firstly permeate into the liquid portion from gas, then disperse into the solid portion, and finally deposit from six crystallographic facets of the catalyst to form the carbon micro鄄coil. Ke