锂离子电池正极材料LiFePO_4的制备与改性进展.pdfVIP

第28 卷 第11 期 电 子 元 件 与 材 料 Vol.28 No.11 2009 年11 月 ELECTRONIC COMPONENTS AND MATERIALS Nov. 2009 综 述 锂离子电池正极材料LiFePO4 的制备与改性进展 张 震，钟松材 （华南理工大学 化学与化工学院，广东 广州 510640） 摘要: 综述了锂离子电池正极材料 LiFePO4 的七种制备方法及其研究进展，评述了各种方法的优缺点。讨论了 LiFePO4 改性研究的最新成果，包括物理掺杂和体相掺杂，分析了各种改性方法提高 LiFePO4 电导率和电化学性能 的可能机理，其中体相掺杂改性机理还存在一些争议。并对 LiFePO4 的研究方向进行了展望。 关键词: 锂离子电池；LiFePO4 ；综述；正极材料；改性 doi: 10.3969/j.issn.1001-2028.2009.11.020 中图分类号: TM912.9 文献标识码:A 文章编号:1001-2028 （2009 ）11-0071-05 Research progress in preparation and modification of LiFePO4 cathode material of lithium ion batteries ZHANG Zhen, ZHONG Songcai (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China) Abstract: Seven preparation methods for the LiFePO4 cathode material of lithium ion batteries are reviewed, as well as their corresponding recent research progresses, and their advantages and disadvantages are presented. The latest achievements of modification research including physical doping and supervalent-cation doping for LiFePO4 are introduced. The possible mechanisms of modification to improve the conductivity and electrochemical properties of LiFePO4 are investigated, however, there are some divergent views on the modification mechanism of supervalent-cation doping. The research direction of LiFePO4 is also prospected. Key words: lithium ion battery; LiFePO4 ; review; cathode material; modification [1] 自从Padhi 等 提出磷酸亚铁锂可用于锂离子电 法。首先将锂源、铁源和磷源充分混合均匀，然后 池正极材料以来，由于其