CuInS2石墨烯混合物的合成及其在太阳能电池中的应用（英文）.pdfVIP

2015年 1月 安徽大学学报 (自然科学版) January2015 第39卷 第 1期 JournalofAnhuiUniversity(NaturalScience Vo1．39No．1 doi：10．3969／j．issn．1000—2162．2015．01．013 SynthesisofCulnS2nan0crystal／graphenenano—networkcounter electrodesforenhancedefficiencydye—sensitizedsolarcells HUA Jian ，IdN Yun-xiang ，ZH()U Lei，YANG Xiao，ZUOXue—qin ，LIGuang， (1_SchoolofPhysicsandMaterialsScience，AnhuiUniversity，Hefei230601，China； 2．AnhuiKeyLaboratoryofInformationMaterialsandDevices，Hefei230601，China) Abstract： CulnS2 nanocrystals have been successfully synthesized through a facile solvothermalmethod in differentsolventsystems．Theas—prepared CulnSepowderswere characterized by X—ray diffraction and were used as counter electrode to fabricatedve— sensitized solar cells． It WaS found thatethylene glycolwas the optimalsolventfor synthesizingCulnSebecausethepowerconversion efficiencyofthecellusing thisCulnS2 powderascounterelectrodecouldreach5．49 ，whichwassuperiortoothers．TheCuInS， powdersynthesized in ethylene glycolwasmixed with reduced grapheneoxideto form CulnSenanocrystal／reducedgrapheneoxidenanocompositesforenhanceitsperformancein dye～sensitized solar cells． Transmission electron microscopy demonstrated thatCuInS， nanocrystalsweregrownalonggraphenenetworks．Itwasfoundthatthisnanocomposites achievedhigherpowerconversion efficiency (6．28Y00)，whichwascomparabletothe conventionaldeviceusingplatinum ascounterelectrode(6．90 )． Keywords：CuInS2；counterelectrode；dye—sensitizedsolarceils(DSSC)；reducedgraphene oxidenanocomposites；powerconversion efficiency CLCnumber：Q946．84；Q946．5 Documentcode：A ArticleID2015)0l一0083—09 CulnS2／石墨烯混合物的合成 及其在太阳能电池中的应用 华 健 ，林运祥 ，周 雷 ，杨 晓 ，左学勤 ，李 广 (1．安徽大学 物理与材料科学学院