Fenton试剂生成_OH的动力学研究.pdfVIP

第 4 卷第 5 期 环境污染治理技术与设备 Vol . 4 , No . 5 2 0 0 3 年 5 月 Techniques and Equipment for Environmental Pollution Control May 2 0 0 3 Fenton 试剂生成 ·O H 的动力学研究 1 ,3 2 1 程丽华 　黄君礼 　倪福祥 ( 1. 青岛建筑工程学院环境工程系 ,青岛266033 ; 2 . 哈尔滨工业大学市政环境工程学院 ,哈尔滨 150090 ; 3 . 中国海洋大学环境科学与工程学院 ,青岛 266003) 摘 　要 　通过试验研究确定了 Fenton 试剂中羟基自由基 ·OH 生成的动力学规律 ,系统考察了 Fenton 体系中三个主要 因素 :H O 浓度 、FeSO 浓度 、p H 值对羟基自由基 ·OH 生成规律的影响情况 ,结果表明 ,这三个因素对羟基 自由基的生成均 2 2 4 有较大的影响 ,在实际生产过程中需加以严格控制 , 以保证最佳的处理效果 。 关键词 　Fenton 试剂 　羟基自由基 ·OH 　动力学 Generation kinetics of hydroxyl radicals by Fenton ’s reagent 1 ,3 2 1 Cheng Lihua 　Huang Junli 　Ni Fuxiang ( 1. Department of Environmental Engineering , Qingdao Institute of Architecture and Engineering , Qingdao 266033 ; 2 . School of Municipal Environmental Engineering , Harbin Institute of Technology , Harbin 150090 ; 3 . College of Environmental Science and Engineering , Ocean University of China , Qingdao 266003) Abstract 　Generation kinetics of hydroxyl radical ( ·OH) by Fenton ’s reagent was studied . The effect of three kinds of major factors , such as p H and the concentrations of H O and FeSO on generation law of ·OH was studied 2 2 4 too . The results showed that these three kinds of factors played a significant role on the generation of hydroxyl radical . Therefore , these factors should be controlled strictly so that optimum results would be obtained