金纳米颗粒对于环己醇的气相选择性催化氧化.doc

金纳米颗粒对于环己醇的气相选择性催化氧化 闫晓庆，，,* 浙江大学化学系，， *Email: jfan@zju.edu.cn 环己醇的氧化产物环己酮是重要的化工原料，不仅是工业上制造尼龙、己内酰胺和己二酸的主要中间体 Fig. 1 A, B and C TEM images of AuNPs/FDU-12 and particle size distribution of AuNPs. D Catalytic performance of AuNPs/FDU-12 in gas-phase cyclohexanol oxidation using O2 as the oxidant. 关键词：纳米金；氧气；环己醇；催化氧化；气相反应 参考文献 [1] G. Jeon and J. Ghung.?Appl. Catal.?115? 1994 , p. 29. [2] D. Santhanaraj ? C. Suresh ? P. Vijayan ? N. Venkatathri ?K. Shanthi?Reac Kinet Mech Cat 2010 Gas-phase selective cyclohexanol oxidation using gold nanoparticles Xiaoqing Yan, Shaodan Xu, Renhong Li, Jie Fan* Department of Chemistry, Zhejiang University, Hangzhou, 310027 The catalytic properties of gold nanoparticles were investigated in gas-phase cyclohexanol selective oxidation using molecular oxygen as the oxidant. The gold catalysts show promising activity at relatively low reaction temperature 180 oC ~ 250 oC , and they are all highly selective for such transformations selectivity 99.5% . Importantly, the optimal size for gold nano-catalyst loaded on large-pore mesoporous silica is in the range of 5 ~ 6 nm, smaller or larger will both lead to worse catalytic activity.