铈对化学镀Co_Ni_P合金薄膜结构及磁性的影响.pdfVIP

4 Ju .l 2009 P lating and F in ishing V o.l 3 1 N o. 7 Seria lN o. 196 : 2009) CoNiP 宣天鹏, 贾 韦 ( , 230009) :利用等离子发射光谱仪电子能谱仪X射线衍射仪和振动样品磁强计等分析了 C e 对 学 镀 CoN iP 合金层成分结构和磁性能的影响结果表明: 随镀液中 ( Ce) 的增加, 学镀 CoN iP 镀层中的CeCo和N i含量有所增加, P的含量则相应降低; 镀层由非晶态CoN iP 合金镀层转变成 了具有微晶晶态结构的C oN iPCe合金镀层稀土 C e的加入提高了镀层的饱和磁 强度和矫 顽力, 降低了剩余磁 强度 : 铈; 学镀 CoN iP; 晶体结构; 磁性 : TQ 153. 2 : A Effect ofCerium on Structure andMagnetic Properties ofElectrolessPlatingCoNiP Alloy Films XUAN T ianpeng, J A W ei ( School of M ater ia l Science and Eng ineering, H efe iU niversity of T echno logy, H efe i 230009, Ch ina) Abstract: T he effects of cerium on the chem ical com position, structure and m agnetic characterist ics of electro less CoN iP a lloy coatingsw ere stud ied by using plasm a transm itting spectrograph, e lectron energy spectrom eter, Xray d iffractom etter and v ibrat ing sam ple m agnetom eter. The resu lts show thatw ith the in crease of cerium in the plating bath, the P content in the alloy coat ings decreases, and Ce, Co and N i contents in the a lloy coat ings increase, as a resul,t the m icrostructure of the alloy coat ings are changed from an am orphous structure to a m icrocrysta lline and crysta lline structure, the saturatedm agnetic intensi ty and coerciv ity of the coatings are increased w ith adding of the rare earth e lem en t cerium, and the rem a nent m agnetic intensity of the coat ings are decreased m eanw hile. Key ord: cerium; CoN iP electro less p lating; crystalline structure; m agnetic property , , ,