功能金属-有机化合物的合成与研究-基础研究.doc

基础研究 成果名称 功能金属-有机化合物的合成与研究 联系人 展树中 电 话 电子邮件 shzhzhan@scut.edu.cn 学科领域 本课题涉及到金属-有机化学，材料化学等，属于化学与材料的交叉领域。 应用背景 功能有机-金属化合物之所以成为当今多学科交叉领域的研究热点而倍受人们关注，一方面这种化合物具有复杂的电子构型和结构、、、、 创新点 合成出一系列功能金属-有机化合物。 测试它们的组成，结构和性质。 化合物光，电和磁性能的研究和应用。 代表性论文 1. Qi-ying Lv，Wei Li, Shu-Zhong Zhan*, Jian-Ge Wang, Jiayin Su. Chemistry?of?tetracyanoethylene?(TCNE):?from?TCNE?to?dicyanomethylacetate. J. Organomet. Chem., 2008， 693，(SCI, IF =2.53) 2. Shuzhong Zhan*, Desheng Sun, Jiange Wang, Jieyu Zhou, AnQi Liang. Synthesis, crystal structures and magnetic properties of a series of new cyano-bridged complexes derived from templates [Ni(CN)4]2- and [Co(III)(CN)6]3-. J. Coord. Chem., 2008, 61, 550-562. (SCI, IF =1.03) 3. Yongqin Song, Qiying Lv，Shuzhong Zhan*, Jianwen Xu. [Cu2((-Cl)((-dppm)2((2-TCNQ)}, a charge transfer compound derived from a donor with a copper dimer. Inorg. Chem. Commun., 2008, 11, 672-674. (SCI, IF =1.90) 4. Wei Li，Shu-zhong Zhan*, Jian-ge Wang, Wen-yuan Yan, Yuan-fu Deng. The isolation and properties of an unexpected cyano-bridged complex [Cl3CoII((-CN)CoII(dppm)2(H2O)](C2H5OH. Inorg. Chem. Commun., 2008, 11, 681-683. (SCI, IF =1.90) 5. Carl Redshaw, Shuzhong Zhan, Sophie H. Dale, Mark R.J. Elsegood. Bis(imido) rhenium complexes bearing C- or N-capped ‘tripodal’ ligands: Bi- versus tri-dentate ligation. Inorg. Chem. Commun. 2008, 11, (in press; DOI: 10.1016/j.inoche.2008.03.020) (SCI, IF =1.90) 6. Shu-zhong Zhan*, Jian-ge Wang, Bing Long, Hai-xia Shu, Wen-yuan Yan, Xin-jia Feng. The assembly, synthesis and properties of a trinuclear cyano-bridged CuII-MoIV-CuII complex. J. Coord. Chem., 2008, 61, (in press, 论文编号：GCOO-257195). (SCI, IF =1.03) 7. Shu-zhong Zhan*, Wei Li, Jian-ge Wang, An-qi Liang, Yuan-fu Deng. Assembly of cyano-bridged Cu(II)/Cu(II) and Cu(I)/Cu(II) compounds obtained by controlled ration of cyanide. J. Organometallic Chem., 2007, 692, 3568-3573. (SCI, IF =2.52) 8. Shu-zhong Zhan*, Jian-ge Wang, Yong-qin Song, Qi-ying Lv, You Song, Jia-yin