大分子缓凝剂对建筑石膏水化进程的影响和缓凝机理.pdfVIP

· 896 · 硅 酸 盐 学 报 2008 年 第36 卷第7 期 硅 酸 盐 学 报 Vol. 36 ，No. 7 2 0 0 8 年 7 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY J u l y ，2 0 0 8 大分子缓凝剂对建筑石膏水化进程的影响及缓凝机理 彭家惠，张建新，陈明凤，吴 莉，瞿金东 (重庆大学建筑材料系，重庆 400045) 摘 要：研究了大分子缓凝剂(骨胶)对建筑石膏水化进程、液相离子浓度与过饱和度及二水石膏晶体形貌的影响，结合X 光电子能谱分析技术对其缓 凝机理进行了分析。结果表明：骨胶能抑制建筑石膏早期水化，使其水化放热减缓，早期水化率降低，凝结时间延长；骨胶对二水石膏晶体形貌影响 较小，但使二水石膏晶体尺度明显增大；骨胶与二水石膏晶核表面钙元素作用，在其表面形成化学吸附层，降低晶核表面能，抑制二水石膏晶核生长， 使建筑石膏水化进程变缓。 关键词：石膏；缓凝剂；水化进程；晶体形貌；缓凝机理 中图分类号：TU526 ；TQ177.3 文献标识码：A 文章编号：0454–5648(2008)07–0896–05 INFLUENCE OF MACROMOLECULE-TYPE RETARDERS ON THE HYDRATION PROCESS OF BUILDING GYPSUM AND ITS RETARDING MECHANISM PENG Jiahui，ZHANG Jianxin，CHEN Mingfeng，WU Li ，QU Jindong (Department of Construction Materials, Chongqing University, Chongqing 400045, China) Abstract: The effect of macromolecule-type retarder bone glue on the hydration process, ion concentration in liquid phase and super- saturation degree, and crystal morphology of dehydrate of building gypsum was investigated. Furthermore, by using the X-ray photo- electron spectroscopy technique, its retarding mechanism was also studied. The results indicate that the addition of bone glue retards the early hydration of building gypsum, which leads to a delay in the hydration heat evolution. It can also decrease the hydration ratio at in the early stage and the prolong induction period of building gypsum. Bone glue has a minor effect on the crystal morphology of dehydrate and a lower negative effect on the strength of hardened gypsum paste than low molecule-type retarder. But it causes the large crystal sizes. Bone glue interacts with the Ca element on the crystal nuclei surface of dehydrates an