DMF用量对聚氨酯湿法成膜的性能及微观结构的影响.pdfVIP

32 卷第5 期 西 部 皮 革 Vol.32 No.5 第 5 期 2010 年3 月 WESTLEATHER Mar.2010 DMF 用量对聚氨酯湿法成膜的性能及微观 结构的影响 1 2 2 马兴元 ，吕凌云 ，李哓 (1.浙江温州轻工研究院，浙江温州325003 ；2. 陕西科技大学资源与环境学院，陕西西安710021） 摘 要：研究了不同DMF 用量下所得聚氨酯湿法成膜的性能，并用多媒体显微镜观察了其微孔结构。 结果表明，随着DMF 用量的增大，和水交换后，聚氨酯湿法成膜的微孔孔径逐步增大，通透孔的数量 增加，使聚氨酯湿法成膜的透气性能和吸湿性能逐步提高，但是透水汽性能变化不大。同时，由于聚氨 酯湿法成膜中微孔的孔径增大，通透孔的数量增加，使膜在结构上的连续性变差，导致力学性能逐渐 降低。 关键词：湿法成膜；聚氨酯；二甲基甲酰胺（DMF）；微观结构 中图分类号：TS 565 文献标识码：A 文章编号：1671-1602 （2010）05-0007-05 Impact of the Amount of DMF on the Properties and Microstructure of Wet-forming Polyurethane Membrane 1 2 2 MA Xing-yuan , LV Ling-yun , LI Xiao (1.Zhejiang Wenzhou Research Institute of Light Industry,Wenzhou 325003, China;2. College of Resource Environment ，Shaanxi University of Science and Technology ，Xian 712081, China） Abstract: The performances of wet-forming polyurethane membrane by using different amount of DMF were studied, and the microporous structures were observed by multi-media microscope.The results showed that with the amount of DMF increasing, after exchanging with water, the aperture and the number of per－ meable micropore of wet-forming polyurethane membrane increased gradually, resulting in the promoting of air permeability and moisture absorption properties, but little change in the performance of water vapor permeability. However, the structure continuity of wet-forming polyurethane membranes was weaken, and mechanical properties decreased. Key words: wet-for