碳纳米管负载氧化铋的制备及催化二硝酰胺铵热分解的研究.pdfVIP

维普资讯 第36卷 第5期 人 工 晶 体 学 报 Vo1．36 No．5 ’2007年 l0月 JOURNAL OF SYNTHETIC CRYSTALS 0ctober．2007 Preparation ofCarbon NanotubesSupporting Bismuth OxideNanometerParticleand Its Catalysison ThermalDecomposition 0InA●m m oni■um lO…initram i■d’e LIXiao一如 ，YANGYan，YANGRong-jie (SchoolofMaterialsScienceandEngineering，BeijingInstituteofTechnology，Beijing100081，China) (Received16May2007，accepted22June2007) Abstract：Carbonnanotubes(CNTs)supportingbismuthoxide(Bi2O3)nanometerparticle(Bi2O3／ CNTs)wasprepraedbythemicrowaveradiationmethod．Bi2O3／CNTsnanometerparticlewasdetermined bymeansofscanelectronmicroscopy (SEM)，X—rayphotoelectronspectroscopy (XPS)andX—ray diffraction(XRD)．ThecatalyticpropertyofBi203／CNTsnanometerparticleonthemraldecompositionof ammoniumdinitramide(ADN)WasinvestigatedbyTGandDSC．TheresultsshowthatnanometerBi2O3 Was coateduniformlyonhtesurfaceofCNTs．AveragesizeofnanometerBi2O3iS8nm．Initial themr al decompo sitiontemperatureand endingthemr al decomposition temperatureofADN decrease 12．8~C and 29．3~C，respectivelywhenadditionamountofBi2O3／CNTsnanometerparticleis3％．NH4N(NO2)2 NH4NO3+N2O isdominna treactionofinitial themr al decompositionofADN． Keywords：crabonnnaotubes(CNTs)；Bi2O3；support；ammonium dinitramide(ADN)；themral decomposition CLCnumber：TJ55：TQ024 Docmu entcode：A ArticleID：1000-985X(2007)05—1127-05 碳纳米管负载氧化铋的制备及催化二硝酰胺铵热分解的研究 李晓东 ，杨 燕，杨荣杰 (北京理工大学材料科学与工程学院，北京 100081) 摘要：采用微波辐射法制备了沉积于碳纳米管(CNTs)表面的氧化铋 (Bi0，)纳米粒子(BiO，／CNTs)，用扫描电子 显微镜(SEM)、光 电子能谱 (XPS)和x射线衍射 (