利用破乳法预处理高浓度难降解平整废液的试验的研究.pdfVIP

利用破乳法预处理高浓度难降解平整废液的试验研究 1 1 2 侯红娟 李恩超 邱兆富 （1.宝山钢铁股份有限公司研究院，上海 201900 ；2.华东理工大学资源与环境工程学院，上海 200237 ） 1 摘 要 平整液是湿平整过程中采用的重要介质，该废水 COD 高，且多为小分子有机物，不易被超滤膜所截留， 对于此类废水，国内外尚无成熟的处理工艺，大多将其稀释后与其它废水混合处理。本研究针对某公司采用的高浓 度难降解的平整液废水，比较了加酸破乳和不同混凝剂混凝破乳作为预处理工艺对COD、BOD5 、油以及B/C 等参 数的处理效果。通过优化试验，综合考虑药剂投加量、COD 去除率以及反应后处理水的B/C 等因素，选定PFS 作 为最佳破乳剂，其投加量为8.0g/L，COD 去除率为45.8 ％，出水B/C 提高至0.38，可以满足后续生化处理的要求。 关键词 平整液 混凝 破乳 可生化性 预处理 Study on the Pretreatment of High-Strenth and Refractory Waste Tempering Lubricant with Demulsification Process Hou Hongjuan1 Li Enchao1 Qiu Zhaofu2 (1.Research Institute Baoshan Iron Steel Co., Ltd., Shanghai, 201900; 2.College of Resource and Environmental Engineering, East China University of Science and Technology, Shanghai, 200237) Abstracts Tempering lubricant is one of the important medias during wet temper rolling process. The COD content is very high and mostly composed of low molecular organics, so the wastewater is difficult to be rejected by ultrafiltration membrane. There have not been mature treatment processes for this kind of wastewater, which is generally treated mixed with other wastewater . In this study, aming at the the high strength and refractory waste tempering lubricant adopted in a cold rolling plant, acid demulsification and coagulation demulsification as the pretreatment process to reduce COD and improve B/C. According to optimized experimental results, considering the dosage of coagulant, COD removal rate and B/C, PFS was chosen as the best coagulant and the optimal dosage was 8g/L. Under the optimal experimental conditions, COD removal of 45.8% realized and the effluent B/C was impro