氧化镁形貌对取向硅钢磁性能的影响.pdfVIP

工艺·技术·应用 氧化镁形貌对取向硅钢磁性能的影响 王 晨，付 骏，陈武山，罗朝林 （福州大学材料科学与工程学院，福建福州 350108 ） 摘 要：采用球状、短棒状和薄片状的三种氧化镁配制成涂液涂布于取向硅钢板，经高温退火形成硅酸镁 底层。采用扫描电子显微镜（SEM ）、硅钢铁损测试仪等手段，研究初始颗粒形貌为球状、短棒状和薄片状的三 种硅钢涂布用氧化镁对硅酸镁底层和取向硅钢磁性能的影响。结果表明，球状氧化镁团聚程度低，活性大，涂 敷性好，形成的硅酸镁底层致密均匀，附着性好，硅钢铁损低，磁感应强度高。 关键词：取向硅钢；氧化镁；硅酸镁底层；磁性能 中图分类号：TM275 文献标识码：A 文章编号：1001-3830(2015)03-0044-03 Effect of particle morphology of magnesia on the magnetic properties of grain-oriented silicon steel WANG Chen, FU Jun, CHEN Wu-shan, LUO Chao-lin College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China Abstract: Three kinds of magnesia (spherical, clubbed and lamellar) were used to form forsterite on the grain-oriented silicon steel after high temperature annealing. Effects of primary particles morphology of magnesia on the properties of the forsterite underlayer and grain-oriented silicon steel were investigated by SEM and iron loss tester. The morphologies of magnesia primary particles were spherical, clubbed and lamellar. Results show that the spherical magnesia has the lowest conglobation, the highest activity and the best coating performance, thus the forsterite with finer homogeneous and good binding to the steel substrate can be obtained. The silicon steel used spherical magnesia has the lowest iron loss and the highest magnetic induction intensity. Key words: grain-oriented silicon steel; magnesia; forsterite; magnetic property 专用氧化镁的原料主要有菱镁矿、白云石、海水或 1 引言 盐湖卤水、含镁工业副产品等，传统的制备方法主 取向硅钢作为电力电子行业中重要的金属软 要有以卤水为原料的卤水-碳铵法、以白云石为原 磁材料，因其生产工艺复杂、需要严格控制的因素 料的碳化法等，近年来也有