巴基管复合水泥基材料的力学性能及其显微结构.pdfVIP

第六届 全国土木工程研究生学 术论坛 清华大学 2008 巴基管复合水泥基材料的力学性能及显微结构 1 1 罗健林 ，段忠东 (1.哈尔滨工业大学土木工程学院, 黑龙江哈尔滨150090) 摘 要: 巴基管复合水泥基材料是一种新近发展起来的功能复合材料。本文采用表面活性剂超声分散法制备出五 组多壁巴基管 (MCNT)分散液，然后用浇注成型法使MCNT与水泥基体复合，制成了相应的巴基管复合水泥基材 料 (MCNT/CM) 。研究了不同MCNT掺量下MCNT/CMs试件的抗折、抗压力学性能，实验结果表明： MCNT 的加 入使得水泥基体抗折、抗压强度均有一定的提高，最大提高幅度可分别达34.58%、21.70% 。对MCNT/CMs试样断 口形貌进行了SEM观察，以探讨其宏观力学性能的内在微观机理，SEM显微结构表明：MCNT在基体中的分散性 及与水化产物界面结合力对相应MCNT/CM 的力学性能影响最大，分散均匀的MCNT在水泥基体间能发挥较好的 纤维拔出效应及桥联增韧效果。这些研究成果对MCNT应用研究拓展及传统建筑结构材料新的应用发展都将有一 定意义。 关键词: 巴基管；水泥；纳米复合材料；力学性能；微观结构 The Microstructures And Mechanical Properties of Multi-walled Carbon Nanotube/Cement Material (MCNT/CM) LUO Jianlin, DUAN Zhongdong (School of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China) Abstract: Carbon nanotube reinforced cement material is a newly developed functional composite. Here, multi-walled carbon nanotube (MCNT)/cement material (MCNT/CMs) with five different loadings of MCNT were fabricated with surfactant ultrasonic dispersion process and mix cast method. The flexural and subsequently compressive strengths of five groups MCNT/CMs were explored, results demonstrate that, some low concentration MCNT incorporation has some reinforcement mechanism on the cement matrix, and the maximal enhancement of the flexural and subsequent compressive strength of MCNT/CM, compared with that of the reference, is around 35 % and 22 %, respectively. SEM microstructures of two MCNT/CM samples were observed after mechanical testing implementation to investigate their micro-scale mechanism, SEM micrographs reveal the dis