扫描电化学显微镜对铁自组装膜电化学表征刘秀玉.pdfVIP

21 3 腐蚀科学与防护技术 Vo.l 21No. 3 2009 5 CORROSION SCIENCE AND PROTECTION TECHNOLOGY M ay. 2009 1, 2 1 1 1 刘秀玉 , 马厚义 , 陈慎豪 , 李文静 1, 250010; 2, 250014 : ( SECM ) ( SAM s) . , / . 01 m ol/L HC lO - 4 167165e- 9A - 2146e- 10A. , , SAM s, , . : ; ( SAM s); ( IM ); ( SECM ) : TG1746 : A : 2009) ELECTROCHEM I CAL CHARACTERIZATION OF SELFASSEMBLED MONOLAYERS ON IRON SURFACE BY SECM 1, 2 1 1 1 LIU X iuyu , MA HouY i, CHEN Shenhao, LIW enjing 1D ep artmen t of Chem is try, Shandong Un iv ersity, J inan 250100; 2Shandong A cademy of S ciences, J inan 250014 Abstract: The performance of corrosion inh ib ition of selfassemble monolayers( SAM s) of mi i azoline forme on iron substrate w as characterize by means of scann ing electrochem icalm icroscopy( SECM ). The line scanning on the iron surface using SECM may be use to investigate the h igh graph ics of SAM s on electro es through etecting the values of Fara ay current on the tip. The expermi entsw ere performe at selecte heights of them icroelectro e above the iron substrate. The substrate generation/ tip collection expermi ent ( SG/TC) is then perform e . The values of the tip current of peaks on the bare iron electro e an on the one mo ifie w ith SAM s in 01 mol/L HC lO w ere - 167165e- 9Amps an - 2146e- 4 10Amps, respectively. The resu lts also show e that the values of tip current of peak ecrease w hen iron substrate wasmo ifie w ith SAM s. The reaso