利用過氧化氫与磷酸結合微波改質廢棄碳纖維及其處理水中染料之的研究.pdfVIP

利用過氧化氫和磷酸結合微波改質廢棄碳纖維及處理水中染料 之研究 1 *2 廖思淳 ，郭昭吟 1. 雲林科技大學環境與安全衛生工程系碩士生，臺灣 2. 雲林科技大學環境與安全衛生工程系副教授，臺灣 联系方式：+886-5-534-2061 ext 4481 摘要：本研究以過氧化氫結合磷酸利用微波法改質廢棄碳纖維(WCF) ，並吸附水中反 應性染料RB19 ，探討改質前後廢棄碳纖維之物理特性及吸附情形。由物性分析得知，經高 瓦數微波改質後之樣品，表面有明顯孔洞產生，且樣品製備率皆有60% 以上，表示微波技術 可在短時間達到改質成效具有可行性，經由熱重分析實驗可看出，改質過後之樣品熱裂解溫 度有明顯提升，推測是由於高溫微波過程中，已將廢棄碳纖維表面中不固定碳燒失而致，此 結果有利於樣品後續回收再利用。經吸附實驗結果得知，於 57℃、pH=7 ，以900 W(9HP) 微波之樣品吸附量為321 mg/g 最佳，皆相較WCF 有明顯提升，並得知吸附效果與溫度、時 間、樣品微波瓦數有關，且本研究經模擬，較符合Fruendlich 等溫吸附方程式及擬二階動力 方程式，屬於多層吸附。 關鍵字：廢棄碳纖維 微波 磷酸 過氧化氫 吸附 Adsorption of aqueous dye RB19 using modified waste carbon fiber by phosphoric acid and hydrogen peroxide adding microwave heating Abstract: Activation of waste carbon fiber by microwave method with phosphoric acid and hydrogen peroxide and adsorption of aqueous dye RB19 using said modified waste carbon fiber was investigated. First, the specific surface of modified waste carbon fiber by thermal microwave heating method was pores obviously and the percent yield was over 60%. It was feasible to microwave technology of modified process could be good effect. In thermal gravimetric analysis, pyrolysis temperature of modified waste carbon fibers was more than original waste carbon fiber, because unfixed carbon from waste carbon fiber surface burned by thermal microwave heating process and the result indicated that those modified waste carbon fibers were conducive to recycle and reuse. The experimental results indicated that the highest capacity of adsorption under 57 ℃, pH=7, 9HP was 320 mg/g and the capacity of adsorption increased with temperature, time, microwave wattage increased. The simulation of experimental data showed that Fruendlich model for equilibrium showed multilayer ads