ICP-MS法在钢铁合金中五种轻稀土元素的分析的应用.pdfVIP

ICP-MS 法在钢铁及合金中五种轻稀土元素的分析应用 于媛君 亢德华 王铁 顾继红 杨丽荣 （鞍钢股份有限公司技术中心，鞍山 114009 ） 1 摘 要 研究建立了 ICP-MS 同时测定钢铁及合金中五种轻稀土：镧、铈、镨、钕、钐元素含量的分析方法。在最 佳化的 ICP-MS 仪器条件下，探讨了稀土测定中的多原子离子干扰和 Fe 的基体效应，采用标准加入法、基体匹配 法和内标法有效地抑制基体效应和补偿分析信号的漂移。当基体浓度≤0.1 ％时，各元素加标回收率在 99.10 ％～ 100.4％之间，各元素检出限分别为：La 0.02ng/mL，Ce 0.015ng/mL，Pr 0.019ng/mL ，Nd 0.041ng/mL, Sm 0.033ng/mL ， 相对标准偏差均小于 2 %，方法具有良好的精密度、准确度和溯源性。 关键词 ICP-MS 法 测定 钢 镧 铈 镨 钕 钐 干扰 校正 内标 标准加入 The Application of ICP-MS in the Determination of La, Ce, Pr, Nd, Sm Contents in Iron, Steel and Alloy Yu Yuanjun Kang Dehua Wang Tie Gu Jihong Yang Lirong (Technology Center of Ansteel Co.,Ltd., Anshan ,114009) Abstract A method has been developed for the determination of La, Ce, Pr, Nd, Sm contents in iron, steel and alloy by ICP-MS. Under optimizing the operation parameters, the interferences caused by polyatomic ions as well as the matrix effect were investigated. The matrix effect was restrained and the signal drift was compensated by the use of standard addition, matrix match and internal standard method. When the matrix concentration was lower than 0.1%,the recoveries of every element were between 99.10 ％～100.4％, the detection limits were La 0.02ng/mL，Ce 0.015ng/mL，Pr0.019ng/mL， Nd 0.041ng/mL, Sm 0.033ng/mL respectively.The RSDs were lower than 2.0%.The method had good precision, accuracy and traceability. Key words ICP-MS，determination，steel，lanthanum，cerium， praseodymium ，neodymium ，samarium，interference， correction，internal standard，standard addtion 我国有丰富的稀土资源，关于稀土在钢中的应用已有大量的研究报道[1-4]，用稀土这个高技术材料来强 化和提升钢铁传统产业，在低合金钢、合金钢中加入微量稀土，提高钢质增强国际竞争力，把稀土的资源优 势转化为钢材的品种优势和经济优势，具有十分重大的意义。随着冶金技术水平的提高，钢中杂质元素的含 量，特别是硫、氧的含量不断下