Er_3_Yb_3_共掺氟磷酸钙纳米微晶玻璃的高效近红外发光性质研究_英文_.pdfVIP

37 1 昆明理工大学学报( ) Vol． 37 No. 1 第 卷 第 期 自然科学版 2012 2 Journal of Kunming University of Science and Technology (Natural Science Edition) Feb． 2012 年 月  doi :10 ． 3969 /j ． issn． 1007 － 855x． 20 12 ． 0 1． 006 Highly Efficient Near-Infrared Luminescence in Er3 + / Yb3 + Co-Doped Nano-FAP Glass Ceramics 1 1 1 - - ZHANG Jing hui ，J IAO Qing ，WANG Rong fei ， ZHOU Da-cheng1，2 ，Y U Xue1，2 ，QIU Jian-bei1，2 (1． School of Materials Science and Engineering ，Kunming University of Science and Technology ，Kunming 650093 ，China ; 2 ． Key Lab． of Advanced Materials of Yunnan Province ，Kunming University of Science and Technology ，Kunming 650093 ，China) Abstract :Transparent Er3 + / Yb3 + co-doped nano-FAP glass ceramics are prepared ，and their near infrared lu- minescence properties are investigated． After heat-treatment ，it is found through X-ray diffractions and transmis- sions electron microscopy measurements that the Ca (PO )F crystals with mean size of 20 nm are precipitated in 5 4 3 the glass matrix ，and that rare earth ions are incorporated into FAP nano-crystals． Compared with the samples before heat-treatment ，the Er3 + / Yb3 + co-doped glass ceramics give very strong 1． 54 μm near-infrared lumines- cence under 808 nm and 980 nm laser diode excitations ，whose full-width at half-maximum (FWHM)reaches to 75 nm． Moreover ，the relationship between 1． 54 μm near-infrared luminescence of glass ceramics and concentra- tions of Er3 + and Yb3 + is investigated． The highly efficient ne