松香季戊四醇酯与甲基丙烯酸_2_羟乙酯反应研究.pdfVIP

34 , - 2- Vol. 31. No. 1, 2009 - 2- * 余彩莉, 陈 林, 张发爱 ( , 541004) : ( RPE ) - 2- (H EMA )D i ls- A ld r, , HEMA RPE HEMA , : , , , ; , H EMA , , , HEMA RPE HEMA RPE , : ; - 2- ; ; : TQ 433. 43 : A : 1001- 0017( 2009) 0 1- 0034- 03 Study on R action of Rosin P nta rythritol Est r and 2- Hydroxy thylM thacrylat YU C ai- l,i CHEN L in and ZHANG Fa- ai (D epartm en t of M a teria l and Chem ica l Eng ineering, G uilin Universi ty of Techn ology, Gu ilin 541004, C hina ) Ab stract: Rosin p nta rythritol st r ( RPE) h as som carb oxy lgroup s and conjugat doubl bond s in itsmo l cular structur , so it can r actw ith 2 - hydroxy thy lm thacrylat ( HEMA ) , w h ich has hydroxy lgroup and doubl bonds, by st rification and D i ls- A ld r addition r action. Th ff cts of r action tm p ratur and m olar ratio on th r action w r inv stigat d. Th structur of th product w as charact riz d by IR and th th rm al stab ility w as t st d by th rm o- grav mi try (TG) . Th r sults show that as th t m p ratur rising, th st rification and addition rat s in cr as at fix d ratio ofRPE to HEMA, it favors th st rification. A s th m olar ratio ofHEMA in cr as s, th brom in valu is d cr asing continuously, but th acid valu stops dropp ing to som d gr , th is indicat s th at th m olar ratio ofHEMA favors th addition r action. Th IR sp ctrum show s that RPE has r act dw ith HEMA and th TG curv indicat s that th in itial and fina l d com pos t m p ratur s drop slightly. K ey w ord s: Rosin p nta rythritol st ; 2- hydroxy thylm th acrylat ; addition r action; st rification , , 前 言 , , HEMA