水玻璃_矿渣水泥的缓凝剂研究_焦宝祥.pdfVIP

化学建材 Ch emical Buildin g Materials 水玻璃 —矿渣水泥的缓凝剂研究 焦宝祥 (盐城工学院材料系 ,江苏省 盐城市 224003) 摘要 :研究了磷酸盐 、含钙材料对水玻璃 —矿渣水泥的凝结时间的影响 。试验结果表明 ,在常规水玻璃掺量时 ,磷 酸盐不产生缓凝作用 ,其原因是磷酸盐阴离子易与硅酸根离子产生氢键缔合作用 ,从而产生凝聚 。试验中选择的几种 含钙材料在常规的水玻璃掺量内有 良好的缓凝效果 ,含钙材料与水玻璃快速反应生成的凝胶在矿渣表面形成一层凝 胶体保护膜 ,阻止了系统中OH - 对矿渣活性的进一步激发 ,使水化产物的晶核包裹在凝胶中,阻止了其进一步生长 ,从 而延缓了水化产物的大量产生 ,避免了颗粒的进一步聚集 ,使系统的初凝时间延长 ,且对其力学性能无不良影响。 关键词 :碱矿渣水泥 ;缓凝剂 ;磷酸盐 ;含钙材料 Abstract : This a er studies the influence of hos hate , calcareous material on set time of water lass - sla ce p p p p g g ment . The test results show the hos hate does not roduce retardin action under normal addition of water lass , the rea p p p g g son is that anion of hos hate roduces easil h dro en - bonded associatin action with ion of silicic acid radical so as to p p p y y g g produce coacervation . Several calcareous materials chose during test have good retarding result under normal addition of wa ter lass. The el formed from fast reaction between calcareous material and water lass will form a rotectin film of col g g g p g loid on the surface of sla , thus to revent OH - of the s stem excitin sla further more . It also makes cr stallite of h g p y g g y y drate wra in into el , thus sto it