浸出黄铜矿的新工艺研究.pdfVIP

25 3 矿 冶 工 程 Vol. 25 l 3 200506 MININGAN METALLURGICALENGINEERING June 2005 ¹ 范兴祥, 彭金辉, 黄孟阳, 张世敏, 张利波 ( , 650093) : , pH ,0.50 mol/L- 74+ 58 Lm 368 K 100 min600 r/min 25 g/L , 98.00% XR ,, ; , + ,,Ag Ag S,, , 2 : ; ; ; : TF111 : A : 0253- 6099(2005)03- 0058- 05 Study on Innovative Process of Leaching of Chalcopyrite FAN Xing-xiang, PENG Jin-hui, HUANG Meng-yang, ZHANG Shi-min, ZHANG L-i bo ( The Faculty of M aterials and Metallurg ical Engineering , K unming University of Science and Technology , K unming 650093, Yunnan, China) Abstract: Theprocess and mechanism of ammonium persulfate leaching chalcopyrite in the presenceof silver ions as the cata- lystwas studied in this paper. Effects of leaching temperature, leaching time, concentration of ammonium persulfate, particle sizeof chalcopyrite, concentration of silver ions, stirring speed and pH value, etc. on the leaching rate of copper also have been discussed and analyzed. Tests results show that the leaching rate of copper obtained was over 98% under the following conditions with initial concentration of ammonium persulfate 0.50 mol/ L, leaching temperature of 368k, with leaching timeof 100min, particle size of chalcopyritewithin - 74+ 58Lm, concentration of silver ions of 0. 001 mol/ L, stirring speed up to 600 r/ min and pulp density of 25 g/L. The leached residues were then characterized with equipment of EPMA- 1600 and XR . Results show that initialaddition of silver ions remains uniformly distributed in theleachingresidues in theform of silver sulfide, and the elemental sulfur is produced duringthe leach and uniformly distr