管壳型二甲醚合成反应器的二维数学模型.pdfVIP

( ) Vol. 32 No. 5 5 8 Journal of East China U niversity of Science and Technology ( Natural Science Edition) 2 6- 5 : 1 6-3 8 ( 2 6) 5- 5 8- 6 刘殿华, 　应卫勇, 　房鼎业 ( 华东理工大学化工学院, 上海2 237) : 以CO 加氢、CO2 加氢合成甲醇和甲醇脱水生成 甲醚反应为关键反应, CO、CO2 和 甲醚为关键组分, 建立了管壳型 甲醚合成反应器的 维数学模型, 用 维正交配置法求得催化床 内各组分浓度和床层温度随轴向和径向分布, 模拟计算了反应器的操作性能。结果表明: 操作压力、 入塔气量对催化床轴向温度分布有较大影响, 反应进口温度对反应影响不大, 径向温度差基本在 2 ～4 °, 径向浓度差一般不超过 . 1% 。 C : 合成气; 甲醚; 维数学模型; 正交配置解 : T Q223 : A - - Two Dimensional Mathematical Model of Tube Shell Type Dimethyl Ether Synthesis Reactor from Syngas L I U Dian-hua, YIN G Wei-yong, FA N G Ding -ye (School of Chemical E ngineering , E ast China University of Science an Technology , Shanghai 2 237, China) Abstract: T w o-dimensional mathematical model of tube-shell type dimethyl ether ( DME) synthesis 2 reactor w as established, w ith taking hydrogenation of CO, CO and dehydration of methanol to dimethyl ether as the independent reactions and taking CO, CO2 and DME as key components. T he concentrations and temperature profiles in axial and radial direction inside the reaction tube w ere obtained by tw o-dimen- sional orthogonal collocation method. Operation conditions of the reactor w ere simulated. The results show that the temperature profiles in axial direction tube are much influenced by pressure and inlet gas flow and reaction is little influenced by inlet temperature. At last, the radial temperature difference is about 24 C and radial concentration difference is less than . 1% . Key words: syngas; dimethyl ether ; tw o-dimension