臭氧液相氧化同时脱硫脱硝实验研究.pdfVIP

第 30 卷第 12 期 环 　　境 　　科 　　学 Vol . 30 ,No . 12 2009 年 12 月 ENVIRONMENTAL SCIENCE Dec . ,2009 臭氧液相氧化同时脱硫脱硝实验研究 马双忱 ,苏敏 ,马京香 ,金鑫 ,孙云雪 , 赵毅 (华北电力大学环境学院 ,保定 　071003) ( ) 液相氧化分别脱硫脱硝技术进行了实验研究. 结果表明 ,液相中 O 摘要 :在 自制的鼓泡反应器上对臭氧 O3 3 对 NO 能够有效 氧化 ,SO2 的存在对 NO 的脱除具有一定的负面影响 ,而 p H 值对 NO 的脱除率影响较小. [O3 ][NO ] = 11 时 ,NO 脱除率可达到 896 %. p H 在 3～11 范围内,NO 脱除率达 80 %以上. 温度在 20～65 ℃范围内,NO 脱除率不发生明显变化. 结合尾部洗涤装置 后 ,可有效脱除 SO2 和 NOx ,脱硫效率几乎达到 100 % ,在[O3 ][NO ] = 11 时 ,可获得 842 %的脱硝效率. 关键词 :脱硫脱硝 ;臭氧 ;液相氧化 ( ) 中图分类号 :X701 　文献标识码 :A 　文章编号 2009 Experimental Research for Simultaneous Removal of SO2 and NOx by Aqueous Oxidation of O3 MA Shuangchen ,SU Min ,MA Jingxiang ,J IN Xin ,SUN Yunxue ,ZHAO Yi ( School of Environment , North China Electric Power University , Baoding 071003 ,China) Abstract :The removal of SO and NO by aqueous oxidation of O was studied by selfdesigned bubbling reactor . The results show that NO can 2 x 3 be oxidized efficiently by O3 in liquid phase ,while the existence of SO2 has a negative impact on the removal of NO and p H value has a little impact . The NO removal efficiency is 896 % at [O3 ][NO ] = 1. 1. When the rang of p H value is in 311 , NO removal efficiency can be achieved over 80 %. At 2065 ℃, NO removal efficiency has no change . Combining with wet scrubbing tower , SO2 removal efficiency is nearly 100 % and NO removal efficiency is 842 % at [O ][NO ] = 11. SO and NO can be removed effectively by aqueous oxidation of O x