Vectran纤维的热学性能研究.pdf

Vectran 纤维的热学性能研究 1 1,2 1,2,3 杜以军 ，蒋金华 ，陈南梁 （1. 东华大学纺织学院，上海 201620 2. 产业用纺织品教育部工程研究中心，上海 201620 3. 东华大学研究院，上海 201620 ） 摘要 为了解Vectran 纤维的耐热性能，使用热烘箱对其进行了热老化处理，测试了其拉伸性能、失重率，并利用SEM，红 外分析、DSC 手段研究了试样外观、分子结构和热学性能受热老化的影响。结果得出：Vectran 纤维的耐热性能较好，从250 ℃ 开始，其强力开始快速下降；SEM 表明Vectran 纤维受热老化后表面产生纵条，温度越高，纵条越深，最终产生类似劈裂的 效果；红外分析表明：纤维大分子链的侧基C=O 及芳环CH 的振动发生变化，主链中C-O 有可能发生断裂；DSC 表明热老 化处理使Vectran 纤维的熔点有少许提升，这主要是高温提供分子链末端运动的机会，使分子链进一步固相紧缩。 关键词 Vectran 纤维；热老化；拉伸；SEM；红外分析；DSC 中图分类号：TS102.5 文献标志码：A Research on thermal property of Vectran Fiber 1 1,2 1,2,3 DU Yijun ，JIANG JinHua ，CHEN Nanliang （1. College of Textiles, Donghua University, Shanghai 201620; 2. Engineering Research Center of Technical Textiles, Ministry of Education, Shanghai 201620; 3. Institute of Donghua University, Shanghai 201620 ） Abstract Vectran fiber was subjected to heat treatments at different temperature to find out its heat resistance . The impact of temperature on the fiber ’s tensile property and weight loss was investigated. The surface and chemical structure of the fiber were studied. The result shows that the heat resistance of Vectran fiber is very good, its tensile strength starts decreasing at about 250 ℃; the SEM photos tell that strips would appear on the surface of Vectran fiber after treated, and the depth of the stripes would increase by the higher temperature; it can be seen from the ATR-FTIR spectra that 1725cm-1and 1110cm-1 are weaken