具有超疏水性质的图案化Ag膜.pdf

理化学学报(Wuli Huaxue Xuebao) 1296 Acta Phys. Chim. Sin., 2006, 22(10) ：1296 1299 October [Note] 具有超疏水性质的图案化Ag 膜 硕 杨凌露 张茂峰 杨朝晖 张智峰 曹维孝 ( 北京大学化学与分子工程学院, 教育部高分子化学与 理重点实验室, 北京 100871) 摘要 以重氮树脂(DR)/聚丙烯酸(PAA) 自组装膜的微图案作为模板, 通过DNA 和聚二甲基二烯丙基氯化铵 (PDDA)在模板上的层层沉积制备了图案化的DNA 膜. 再在其中进行Ag 的化学沉积得到图案化的Ag 膜. 最后 利用低表面能的十二烷基硫醇对Ag 膜进行表面修饰, 制备了具有超疏水性质的图案化Ag 膜. 其静态接触角达 到约168毅. 关键词： 超疏水, 图案化, 无电沉积, DNA 膜, Ag 膜 中图分类号： O647 Patterned Ag Film with Superhydrophobic Properties BAI, Shuo YANG, Ling鄄Lu ZHANG, Mao鄄Feng YANG, Zhao鄄Hui ZHANG, Zhi鄄Feng CAO, Wei鄄Xiao (The Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China) Abstract Patterned DR(diazoresin)/PAA(polyacrylic acid) SA(self鄄assembly) film was used as template on which a patterned DNA film was prepared by alternate deposition of DNA and PDDA (polydimethyldiallylammonium chloride). Then a patterned Ag film was obtained by means of Ag electroless deposition in the DNA patterned film. After surface modification with n鄄dodecanethiol the patterned Ag film, which exhibits obvious microstructure and nanostrucutre, will possess super hydrophobic properties and the contact angle of water on this surface can reach to about 168毅. Keywords ： Superhydrophobic, Patterning, Electroless deposition, DNA film, Ag film 接触角大于150毅 的超疏水表面在日常和工业 [11鄄12]