化学镀法制备银壳聚苯乙烯微球.pdf

物理化学学报(Wuli Huaxue Xuebao) 644 Acta Phys. Chim. Sin., 2006, 22(5) ：644 648 May [Note] 化学镀法制备银壳聚苯乙烯微球 刘惠玉1, 2 陈 东1 唐芳琼1 * 凌 慧1 任湘菱1 1 2 ( 中国科学院理化技术研究所, 北京 100080 ； 中国科学院研究生院, 北京 100049) 摘要 采用一种新的化学镀法合成银壳包覆聚苯乙烯微球, 通过三乙醇胺和银离子络合来减小反应的氧化还原 电位差, 降低银在改性聚苯乙烯微球表面的沉积速率. 采用TEM 、XRD 、UV 等测试手段对样品进行了分析和表 征, 并考察了不同反应条件对实验结果的影响. 实验表明, 该方法可在改性聚苯乙烯微球上包覆均匀的银层. 关键词： 化学镀, 银, 改性聚苯乙烯微球, 三乙醇胺 中图分类号： O641, TB383 Fabrication of Silver Nanoshells on Modified Polystyrene Microspheres through Electroless Plating Approach LIU, Hui鄄Yu1, 2 CHEN, Dong1 TANG, Fang鄄Qiong1 * LING, Hui1 REN, Xiang鄄Ling1 1 ( Technical Institute of Physics and Chemistry, Chinese Academy of Science, Beijing 100080, P. R. China ； 2Graduate School of the Chinese Academy of Science, Beijing 100049, P. R. China) Abstract Modified polystyrene microspheres with silver shells were prepared by a novel electroless plating approach using complexation mechanism of triethanolamine(TEA) and silver ion to reduce oxidation鄄reduction potential difference and slow down the deposition speed of silver on modified polystyrene spheres. These samples were characterized by TEM, UV, XRD, and the synthesis conditions were also investigated. Experimental results show that uniform silver shells can be deposited on the modified polystyrene spheres by this method. Keywords ： Electroless plating, Silver, Modified polystyrene spheres, Triethanolami