拉曼光谱上水的结构以及其与温度的关系.pdf

Semiconductor Physics, Quantum Electronics Optoelectronics, 2011. V. 14, N 1. P. 77-79. PACS 78.30.C- On Raman spectra of water, its structure and dependence on temperature S.M. Baschenko, L.S. Marchenko Institute of Physics, NAS of Ukraine 46, prospect Nauky, 03028 Kyiv, Ukraine E-mail: baschenk@iop.kiev.ua Abstract. Raman spectra of water within the temperature range 20 to 3 C were investigated. Best of all, the complex shape of the obtained spectra was approximated by four (or five) Gaussian-shaped peaks with their positions 3070, 3230, 3440, 3600 (and 3650) cm–1 –1 . The most intensive constituents were 3230 and 3440 cm lines, their total contribution to the Raman spectrum of water is higher than 90%. These lines are the most sensitive to the temperature, too. When the temperature decreases from 20 down to 3 C, the positions of these peaks were shifted from 3232 to 3224 cm–1 and from 3441 to –1 –1 3434 cm , respectively; and the intensity of 3230 cm line was increased approximately by 14% in its magnitude. Keywords: Raman spectra, water structure, temperature, pressure. Manuscript received 07.06.10; accepted for publication 02.12.10; published online 28.02.11. 1. Introduction possibility to