超高分子量聚甲基丙烯酸十二酯的合成.pdfVIP

维普资讯 第 19卷第 4期 青 岛大 学 学报 (工 程 技 术 版 ) JOURNALOFQINGDAOUNIVERSITY (ET) VoI．19No．4 2004年 12月 Dec．2004 AIti：deID：1006—9798(2OO4)O4—0012—06 SynthesisofPoly(DodecylMethacrylate)swith UltrahighMolecularW eight MA Yu—xin～，ZHENG Xi—lai，SHIFeng—mei，LIYue (1．SchoolofEnvironmentalScience Engineering，OceanUniversityofChina，Qingdao266003，China； 2．DepartmentofEnvironmenatlScienceEngineering，QingdaoUniversity，Qingdao266071，China) Abstract：Dodecylmethacrylatewassynthesized asthe intermediatemonomerforthe preparationofPoly(dodecylmethacrylate)sandpoly(dodecylmethacrylate)sweresyn— thesizedwith emulsion polymerization techniques．Intrinsicviscositiesweremeasured andviscosityaveragemolecularweightswerecalculated．Andthenthepolymersofdo- decylmethacrylatewith ultra—high molecular weight (Mr／ 10 ) were synthesized throughorthogonalexperiments．IR SpectraofDodecylMethacrylatemonomerandpol- ymerwereexamined．Thefactorswhich influencethemolecularweightwerestudied． Thestudiesshow thatM r／increaseswiththeinitiatorconcentrationdecreasing，there- ducerconcentration increasesand theemulsifierconcentration increasing．M r／and the conversionincreasewiththereactiontimeprolonged．Thestudiesalsoshow thataddi— tionofanotheremulsifier(TritonX．100)canstabilizetheemulsionandtheM ”ofprod— uctsisenhancedfrom 1．17×10 to1．75×10 ． Keywords：emulsionpolymerization；infraredspectroscopy；poly (dodecylmethacry- late)；ultrahighmolecularweight；orthogonalexperiments CLCnunbet：TQ314．2 Documentcode：A Thepolymersofdodecylmethacrylatewithult