Ce-Pt-Pd不锈钢丝网催化剂的制备与催化性能.pdfVIP

第 30 卷 第 7 期 催 化 学 报 2009 年 7 月 Vol. 30 No. 7 Chinese Journal of Catalysis July 2009 文章编号: 0253-9837(2009)07-0649-05 研究论文: 649~653 Ce-Pt-Pd/不锈钢丝网催化剂的制备与催化性能 陈 敏, 马 莹, 宋 萃, 张 婷, 郑小明 浙江大学催化研究所, 浙江杭州 310028 摘要：采用阳极氧化技术在不锈钢丝网上自生长了一层结构致密的阳极氧化膜, 并以此为载体, 制备出一种高活性、高稳定性 的负载型 Ce-Pt-Pd 催化剂. 考察了该系列催化剂对甲苯、丙酮和乙酸乙酯的氧化活性, 并用扫描电镜、X 射线光电子能谱和程 序升温氧化技术对催化剂进行了表征. 结果表明, 不锈钢丝网载体表面自生长的氧化物膜十分有利于活性组分的负载, 制得的 催化剂具有较高的催化燃烧有机化合物的活性和稳定性. 关键词：不锈钢丝网; 阳极氧化膜; 氧化铈; 铂; 钯; 催化氧化 中图分类号：O643/X7 文献标识码：A Preparation and Performance of Ce-Pt-Pd/Stainless Steel Wire Meshes Catalyst * CHEN Min , MA Ying, SONG Cui, ZHANG Ting, ZHENG Xiaoming Institute of Catalysis, Zhejiang University, Hangzhou 310028, Zhejiang, China Abstract: A catalyst of Ce-Pt-Pd/stainless steel wire meshes was prepared by anodic oxidation techniques, and its catalytic behavior for total oxidation of toluene, acetone, and ethyl acetate was investigated. The catalyst was characterized by scanning electron microscopy, X-ray photoelectron spectroscopy, and O2 temperature-programmed oxidation. The results indicated that the high catalytic activity and stability of the catalyst are caused by taking stainless steel wire meshes as support and whose surface is covered by a porous anodic oxidation mem- brane. This porous anodic oxidation membrane is extremely efficient for supporting active compounds such as Pt, Pd, and Ce on the metal material. The prepared Ce-Pt-Pd/stainless steel wire meshes catalyst showed good catalytic activity and stability for volatile organic com- pound combustion. Key wor