N-羧甲基壳聚糖膨润土复合材料的制备与吸附性能研究.pdfVIP

第 35 卷 第 3 期 Vol.35 No.3 2014 年 6 月 Journal of Ceramics Jun. 2014 第 35 卷 第 3 期 · 309 · N-羧甲基壳聚糖/膨润土复合材料的制备与吸附性能研究 梁红莲 (廊坊师范学院化学与材料科学学院，河北 廊坊065000) 摘 要：以一氯乙酸、壳聚糖、氢氧化钠为主要原料了制备N-羧甲基壳聚糖，并将其负载于膨润土上，制备得到了羧甲基壳 聚糖/膨润土复合材料。利用红外(IR)、扫描电镜(SEM)对复合材料进行了表征。通过复合材料对亚甲基蓝溶液的吸附性能实 验，优化出最佳吸附条件为30 ℃下，pH=8，亚甲基蓝溶液的初始浓度为6 mg/L时的吸附效果最好，达86.80%。 关键词：羧甲基壳聚糖；膨润土；复合材料；吸附 中图分类号：TQ174.4 文献标志码：A 文章编号：1000-2278(2014)03-0309-05 Study on the Preparation and Adsoprtion Properties of Carboxymethyl Chitosan / Bentonite LIANG Honglian (Faculty of Chemistry and Material Science, Langfang Teachers College, Langfang, 065000, Hebei, China) Abstract:N-carboxymethyl chitosan was prepared by using chloroacetic acid, chitosan, and sodium hydroxide as the main raw material, and then carboxymethyl chitosan / Bentonite composite materials loaded on the bentonite was prepared. Infra-red spectrum(IR) and Scanning Electron Microscope(SEM)techniques were ued to characterize the carboxymethyl chitosan/Bentonite composite material. The adsorption test of carboxymethyl chitosan/Bentonite composite materials for Methylene blue solution was investigated. The researches of the exeperimenial results show htat: When the temperature 30 ℃, pH equals 8, and the initial concentration of methylene blue solution of 6 mg/L, the adsorption of rate is 86.80%. Key words:carboxymethyl chitosan; bentonite; composite materials; adsorption 0 前 言 湿性、成膜性、凝胶性等特性，在化工、食品、医 疗、纺织等领域有广泛的应用[5, 6] 。 　　近年来，壳聚糖作为一种新型高分子功能材料