PBTCA及TH-904改性纳米零价铁材料的制备及表征.pdfVIP

·4· 材料导报B：研究篇 PBTCA及TH一904改性纳米零价铁材料的制备及表征* 冯婧微，粱彦秋 (沈阳化工大学环境与安全工程学院，沈阳110142) 摘要 为改善纳米粉体的分散性，使其在高表面能态下稳定存在，以NaBHt液相还原Fe3+制备纳米级零价 铁颗粒。对比采用不加入改性剂、加入改性剂2一膦酸丁烷一1，2，4一三羧酸(PBTCA)和改性剂TH一904，分别制备普通 平均粒径分别为125nln、73nIn和64nln。改性后，由于颗粒粒径减小，引起产品部分氧化，但颗粒得到有效分散。 FT取测试表明，改性后产物中分别出现二种改性剂有效基团，表明改性剂对纳米零价铁有效分散起到了积极作用， 并对该作用进行了分析。 关键词 纳米零价铁改性PBTCATH一904制备表征 中图分类号：X52 文献标识码：A andCharacterizationofFeo Modified Preparation Nanoparticles withPBTCAandTH-904 FENG Jingwei，LIANGYanqiu ofEnvironmentaland ofChemical 110142) (College SafetyEngineering，ShenyangUniversity Technology，Shenyang AbstractTo the andmakethem with surface ofiron improvedispersity high keepstability energy nanoparti— cles，normaliron acid acid(PBTCA)一stabilizedllano- nanoparticles(N-Feo)，2-phosphonicbutane-1，2，4-tricarboxylic TH一904一stabilized reductionmethod．Fur— particles(P-Feo)andnanoparticles(T-Feo)weresynthesizedbyborohydride were examined electron thermore，theycarefully byX-raydiffraction(XRD)，scanning sionelectron transforrninfrared microscope(TEM)，Fourierspectroscopy(FTIR)andenergydispersiveX-rayanaly— sis(EDX)．Thecharacterizationresults thatthe sizeofN_一Fe0，P-FeoandT-Feo is suggestedaverage nanoparticles nin nlTl about125nlTl，73and64 indiameter the are of respectively．Ahhough